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Pregnancy in a patient with uncorrected total anomalous pulmonary venous connection (TAPVC) – A case report and literature review 
Construction of remote dual stereocenters by electrochemical cobalt-catalyzed enantioselective desymmetrization
Abstract The enantio- and diastereoselective construction of two stereogenic centers represents a highly attractive objective in synthetic chemistry. Extensive asymmetric catalytic methods have been developed for the formation of vicinal stereocenters. In contrast, the simultaneous construction of two constitutionally distinct stereogenic centers at remote positions in a single asymmetric catalytic step remains very scarce, owing to the lack of reliable models for distant stereochemical induction for both chiral entities. Herein, we report on an electrochemical cobalt-catalyzed asymmetric hydroacylation of enynes by a desymmetrization strategy that enables the enantio- and diastereo-selective construction of remote dual stereocenters. This unified catalytic platform exhibits broad substrate generality and affords four distinct classes of chiral products, each incorporating two chiral elements: 1,6-central/C–C axial chirality, 1,6-central/C–O axial chirality, 1,5-central/[2.2]paracyclophane planar chirality, and 1,5-central/ferrocene planar chirality.
The impact of spinal versus general anaesthesia on postoperative outcomes following total knee arthroplasty: A systematic review
Microbial activation of the GLP-2R mitigates gastrointestinal inflammation
Troubleshooting facemask fit with virtual reality headsets: Rendell-baker soucek mask revisited 
Genetic insights and mechanistic parallels in gestational diabetes mellitus and type 2 diabetes
Bioinformatics in anaesthesia: A new era of personalised and predictive perioperative care
Distance-decay reveals contrasting effects of land-use types on arthropod community homogenisation
Abstract Homogenisation caused by intensive land-use is one of the drivers of global biodiversity decline. However, the contribution of land-use intensity to insect diversity loss is still largely untested. Therefore, we compare the rate of species homogenisation of ~12.000 arthropod species (using Barcode Index Numbers) from 450 families, using distance-decay relationships. We study communities along an increasing local land-use intensity gradient from forests to managed grasslands, to arable lands and to settlements situated within near-natural, agricultural, and urban regional landscapes. Our approach for incidence data under consideration of incomplete samples identifies that grasslands harbour the most homogenous communities after taking frequency and species traits into account. In contrast, the most modified land-use types, settlements, and arable lands do not differ from forests, and showed the most heterogeneous communities between locations. Large- and low-mobility species communities are the most heterogeneous in space, but patterns are dependent on local land-use. Regional landscapes modify the community response to local land-use types: near-natural landscapes reduce homogenisation, while agricultural landscapes increase homogenisation. Based on our findings we recommend enhanced conservation efforts particularly in managed grasslands to reverse homogenisation, while settlements and arable lands could be considered more in arthropod community heterogenisation.
Artificial intelligence in perioperative pain management: A systematic review
Thiazole-conjugated covalent organic framework membranes enable ultraselective molecular desalination under strongly acidic conditions
A cross sectional study to evaluate the anticipated and experienced pain at the site of spinal needle insertion in patients undergoing elective lower segment caesarean section
Dimensionality-dependent electronic and vibrational dynamics in low-dimensional organic-inorganic tin halides
Abstract Photo-induced dynamics of electronic processes are driven by the coupling between electronic and nuclear degrees of freedom. Here, we construct one- and two-dimensional organic-inorganic tin halides to investigate how dimensionality controls exciton-phonon coupling and exciton self-trapping. The results show that a one-dimensional system has strong exciton-phonon coupling leading to excitation-independent self-trapped exciton emission, whereas a two-dimensional system exhibits over ten times weaker coupling resulting in free exciton emission. The difference originates from enhanced Anderson localization in a one-dimensional system. Femtosecond transient absorption experiments directly resolve room-temperature vibrational wavepackets in a one-dimensional system, some of which propagate along the self-trapped-exciton potential energy surface. A combination of wagging and asymmetric stretching motions (~106 cm -1 ) in tin iodide is identified as such a mode, inducing exciton self-trapping. While no room-temperature wavepackets are observed in a two-dimensional system. These findings uncover the interplay between dimensionality-dependent exciton-phonon coupling and electronic/nuclear dynamics, offering constructive guidance to develop multifunctional organic-inorganic metal halides.
Comparative efficacy of two doses of dexmedetomidine as an adjuvant to ropivacaine in paravertebral block for post-mastectomy analgesia: A randomized, double-blind study
Cluster level entropy enhancement in neutral acetate electrolytes enables economical and durable zinc air batteries
Ketamine–dexmedetomidine total intravenous anaesthesia with NIRS-guided oxygenation in an adult with cyanotic congenital heart disease undergoing craniotomy: A case report
Albumin orchestrates a natural host defence mechanism against mucormycosis
Inactive ryanodine receptors sustain lysosomal availability for autophagy by promoting ER-lysosomal contact site formation
Comparative study of hemodynamic effects of carbetocin and oxytocin in patient undergoing elective lower segment caesarean section under spinal anaesthesia: An observational analytical study
Genomic and physiological signatures of adaptation in pathogenic fungi
Abstract Emerging fungal pathogens have detrimental impacts on crops, animals, and humans. Despite the mounting threat of these emerging fungal pathogens, little is known about their transition from saprotrophic to pathogenic lifestyles. To gain insights into fungal lifestyle transitions, we study the Trichosporonales order, which includes both saprotrophic species and opportunistic human pathogens, as a system to reveal evolutionary adaptations leading to virulence in fungi. Here we use comparative genome analyses and experimental assays to demonstrate that the transition from saprotroph to opportunistic human pathogen is facilitated by adaptive translation. Codon optimization of metabolic genes grants these fungi the ability to quickly adapt to new environments. In this study, we link genomic data with fungal physiology, highlighting the role of adaptive translation in colonizing different environments and suggesting that gene translation optimization plays a critical role in fungal lifestyle evolution.