X-ray emission spectroscopy in liquid jets: A effective tool to probe valence and <i>p</i> -shells in organometallics and the influence of the solvation
Abstract
In this combined experimental and theoretical work, we present state-of-the-art liquid jet experiments based on x-ray emission spectroscopy of the [Fe(CN)6]4− and [Fe(CN)6]3− molecular ions in the hard-x-ray energy range. The ab initio simulations of the valence-to-core and Kβ spectra reveal insights into the valence and metal’s d-shells, respectively. These results open new perspectives for applying spectroscopy to organometallic complexes in order to disentangle and probe various environmental effects, including solvent interactions, pH variations, and ligand field influences and dynamical processes, such as charge transfer or photoinduced ligand exchange reactions such as photoaquation in solution.
Article Details
Journal Info
The Journal of Chemical Physics
American Institute of Physics
Authors (10)
L. Journel
Sorbonne Université, CNRS, Laboratoire de Chimie Physique–Matière et Rayonnement, LCPMR 1 , 75005 Paris,
N. H. Azzouza
Sorbonne Université, CNRS, Laboratoire de Chimie Physique–Matière et Rayonnement, LCPMR 1 , 75005 Paris,
G. Goldsztejn
Université Paris-Saclay, Institut des Sciences Moléculaires d’Orsay ISMO, UMR CNRS 8214 3 , F-91405 Orsay,
R. Dupuy
Sorbonne Université, CNRS, Laboratoire de Chimie Physique–Matière et Rayonnement, LCPMR 4 , 75005 Paris,
J. Palaudoux
Sorbonne Université, CNRS, Laboratoire de Chimie Physique–Matière et Rayonnement, LCPMR 4 , 75005 Paris,
M. Fournier
Sorbonne Université, CNRS, Laboratoire de Chimie Physique–Matière et Rayonnement, LCPMR 1 , 75005 Paris,
S. Carniato
Sorbonne Université, CNRS, Laboratoire de Chimie Physique–Matière et Rayonnement, LCPMR 1 , 75005 Paris,
J. M. Ablett
Synchrotron SOLEIL, L’Orme des Merisiers 2 , Saint-Aubin, BP 48, F-91192 Gif-sur-Yvette Cedex,
J.-P. Rueff
Sorbonne Université, CNRS, Laboratoire de Chimie Physique–Matière et Rayonnement, LCPMR 1 , 75005 Paris,
D. Céolin
Synchrotron SOLEIL, L’Orme des Merisiers 2 , Saint-Aubin, BP 48, F-91192 Gif-sur-Yvette Cedex,