Unveiling street art: A multimodal and multitechnique approach for analyzing and mapping painting materials on large murals

F Francesca Sabatini (National Research Council, Institute of Chemical Science and Technologies “G. Natta”) F Fauzia Albertin (National Research Council, Institute of Chemical Science and Technologies “G. Natta”) B Brenda Doherty (National Research Council, Institute of Chemical Science and Technologies “G. Natta”) L Letizia Monico (AXIS Antwerp X-ray Imaging and Spectroscopy laboratory, University of Antwerp, 2020 Antwerp, Belgium) F Francesca Rosi (National Research Council, Institute of Chemical Science and Technologies “G. Natta”) D David Buti (National Research Council, Institute of Heritage Science, Area della Ricerca di Firenze) A Aldo Romani A Antonio Pecci (National Research Council, Institute of Chemical Science and Technologies “G. Natta”) N Nicodemo Abate (National Research Council, Institute of Heritage Science) M Maria Sileo (National Research Council, Institute of Heritage Science) A Antonio Minervino Amodio (National Research Council, Institute of Heritage Science) N Nicola Masini (National Research Council, Institute of Heritage Science) S Silvia Pizzimenti (Department of Chemistry and Industrial Chemistry, University of Pisa) I Ilaria Degano (Department of Chemistry and Industrial Chemistry, University of Pisa) F Francesca Modugno (Department of Chemistry and Industrial Chemistry, University of Pisa) B Beatrice Campanella (National Research Council, Applied and Laser Spectroscopy Laboratory, Institute of Chemistry of Organometallic Compounds, Research Area of the National Research Council) S Stefano Legnaioli (National Research Council, Applied and Laser Spectroscopy Laboratory, Institute of Chemistry of Organometallic Compounds, Research Area of the National Research Council) L Laura Cartechini (National Research Council, Institute of Chemical Science and Technologies “G. Natta”)

Abstract

Street art murals are increasingly recognized as valuable contemporary artworks, often attaining significant artistic, historical, and social importance. As these murals become integral parts of cultural heritage, finding efficient strategies for their conservation is crucial. However, their typical large surface areas, heterogeneous materials, and high variability in exposure to environmental and pollution factors pose significant challenges in establishing appropriate analytical strategies to obtain the necessary information. This study proposes a multiscale and multitechnique noninvasive approach to investigate and monitor street art murals in situ. By combining portable point techniques—such as external reflection Fourier transform infrared spectroscopy, Raman spectroscopy, visible, near infrared, and short-wave infrared reflectance spectroscopy, and X-ray fluorescence spectroscopy—with visible and near infrared hyperspectral imaging, the mural’s composition across a square meter surface could be analyzed. Additionally, multispectral imaging mounted on a drone provided a global reconstruction and characterization of the overall mural. This method was complemented by microdestructive laboratory analyses of selected samples, using pyrolysis gas chromatography–mass spectrometry and liquid chromatography coupled with diode array detector and tandem mass spectrometry, to further investigate selected samples and support noninvasive results. The approach was applied to the iconic mural “Musica Popolare” (2017) by Orticanoodles in Milan, Italy, revealing detailed information about its pigments, binders, fillers, and degradation. The findings demonstrate the potential of this integrated methodology for the effective material identification, conservation assessment, and short-and long-term monitoring of urban heritage.

Article Details

Volume / Issue Vol. 122, Issue 35
Published September 02, 2025
ISSN 0027-8424
Publisher National Academy of Sciences

Authors (18)

F

Francesca Sabatini

National Research Council, Institute of Chemical Science and Technologies “G. Natta”

F

Fauzia Albertin

National Research Council, Institute of Chemical Science and Technologies “G. Natta”

B

Brenda Doherty

National Research Council, Institute of Chemical Science and Technologies “G. Natta”

L

Letizia Monico

AXIS Antwerp X-ray Imaging and Spectroscopy laboratory, University of Antwerp, 2020 Antwerp, Belgium

F

Francesca Rosi

National Research Council, Institute of Chemical Science and Technologies “G. Natta”

D

David Buti

National Research Council, Institute of Heritage Science, Area della Ricerca di Firenze

A

Aldo Romani

A

Antonio Pecci

National Research Council, Institute of Chemical Science and Technologies “G. Natta”

N

Nicodemo Abate

National Research Council, Institute of Heritage Science

M

Maria Sileo

National Research Council, Institute of Heritage Science

A

Antonio Minervino Amodio

National Research Council, Institute of Heritage Science

N

Nicola Masini

National Research Council, Institute of Heritage Science

S

Silvia Pizzimenti

Department of Chemistry and Industrial Chemistry, University of Pisa

I

Ilaria Degano

Department of Chemistry and Industrial Chemistry, University of Pisa

F

Francesca Modugno

Department of Chemistry and Industrial Chemistry, University of Pisa

B

Beatrice Campanella

National Research Council, Applied and Laser Spectroscopy Laboratory, Institute of Chemistry of Organometallic Compounds, Research Area of the National Research Council

S

Stefano Legnaioli

National Research Council, Applied and Laser Spectroscopy Laboratory, Institute of Chemistry of Organometallic Compounds, Research Area of the National Research Council

L

Laura Cartechini

National Research Council, Institute of Chemical Science and Technologies “G. Natta”