Ultrasensitive Deep‐Ultraviolet Photodetectors Based On Band Engineering and Ferroelectric Modulation

H Han Wu L Lincong Shu (Innovation Center of Gallium Oxide Semiconductor (IC-GAO), College of Integrated Circuit Science and Engineering, Nanjing University of Posts and Telecommunications 1 , Nanjing 210023,) Q Qinghua Zhang S Shulin Sha (College of Physics MIIT Key Laboratory of Aerospace Information Materials and Physics Key Laboratory for Intelligent Nano Materials and Devices Nanjing University of Aeronautics and Astronautics No. 29 Jiangjun Road Nanjing 211106 China) Z Zeng Liu (Electronic-Photonic Smart Sensing Device R&D Team, School of Electronic Information Engineering, Inner Mongolia Key Laboratory of Intelligent Communication and Sensing and Signal Processing, Inner Mongolia University 2 , Hohhot 010021,) S Shan Li (Institute of Solid State Chemistry, Department of Physical Chemistry, Beijing Advanced Innovation Center for Materials Genome Engineering) S Sihan Yan (Innovation Center of Gallium Oxide Semiconductor (IC-GAO), College of Integrated Circuit Science and Engineering, Nanjing University of Posts and Telecommunications 1 , Nanjing 210023,) W Weihua Tang Y Yuehui Wang (Key Laboratory of Biorheological Science and Technology, Ministry of Education, College of Bioengineering) Z Zhenping Wu (State Key Laboratory of Information Photonics and Optical Communications & School of Physical Science and Technology, Beijing University of Posts and Telecommunications 3 , Beijing 100876,) K Kun Lin (Institute of Solid State Chemistry) Q Qiang Li J Jun Miao (Institute of Solid State Chemistry) X Xianran Xing (Institute of Solid State Chemistry)

Abstract

AbstractWide bandgap semiconductors have emerged as a class of deep‐ultraviolet sensitive materials, showing great potentials for next‐generation integrated devices. Yet, to achieve a high photoresponse of deep‐ultraviolet detector without complicated designs at low supply voltage and weak light intensity is challenging. Herein, a new way is designed to fabricate an ultrasensitive vertical‐structured photodetector with epitaxial 7 nm BaTiO3 interlayer and 10 nm Ga2O3 photosensitive layer, realizing the detection to a rare weak deep UV light intensity (0.1 µW cm−2) at a voltage under 4.8 V and demonstrating a surge in responsivity up to 1.1 A W−1 with ultrafast response of 0.24 µs/33.4 µs (rise/decay). A responsivity of 3.8 mA W−1 at 0 V also has been reached. The dark current is suppressed by enlarged conduction band offset and meanwhile the photocurrent is enhanced by unidirectional conducting valance band offset, which formed by BaTiO3 interlayer. BaTiO3 also contributes most to the photoresponse at 0 V through its ferroelectric depolarization electric field. These results provide a path toward high‐sensitive, low‐power‐consumption, and highly‐integrated deep‐ultraviolet detection, beyond conventional ones.

Article Details

Volume / Issue Vol. 37, Issue 29
Published July 01, 2025
ISSN 0935-9648
Publisher Unknown Publisher

Journal Info

Advanced Materials

Unknown Publisher

ISSN: 0935-9648 Physical Sciences

Authors (14)

H

Han Wu

L

Lincong Shu

Innovation Center of Gallium Oxide Semiconductor (IC-GAO), College of Integrated Circuit Science and Engineering, Nanjing University of Posts and Telecommunications 1 , Nanjing 210023,

Q

Qinghua Zhang

S

Shulin Sha

College of Physics MIIT Key Laboratory of Aerospace Information Materials and Physics Key Laboratory for Intelligent Nano Materials and Devices Nanjing University of Aeronautics and Astronautics No. 29 Jiangjun Road Nanjing 211106 China

Z

Zeng Liu

Electronic-Photonic Smart Sensing Device R&D Team, School of Electronic Information Engineering, Inner Mongolia Key Laboratory of Intelligent Communication and Sensing and Signal Processing, Inner Mongolia University 2 , Hohhot 010021,

S

Shan Li

Institute of Solid State Chemistry, Department of Physical Chemistry, Beijing Advanced Innovation Center for Materials Genome Engineering

S

Sihan Yan

Innovation Center of Gallium Oxide Semiconductor (IC-GAO), College of Integrated Circuit Science and Engineering, Nanjing University of Posts and Telecommunications 1 , Nanjing 210023,

W

Weihua Tang

Y

Yuehui Wang

Key Laboratory of Biorheological Science and Technology, Ministry of Education, College of Bioengineering

Z

Zhenping Wu

State Key Laboratory of Information Photonics and Optical Communications & School of Physical Science and Technology, Beijing University of Posts and Telecommunications 3 , Beijing 100876,

K

Kun Lin

Institute of Solid State Chemistry

Q

Qiang Li

J

Jun Miao

Institute of Solid State Chemistry

X

Xianran Xing

Institute of Solid State Chemistry