Ultrafast and Universal Synthetic Route for Nanostructured Transition Metal Oxides Directly Grown on Substrates

S Si Heon Lim G Geunwoo Kim (Department of Materials Science and Engineering Korea University Seoul 02841 Republic of Korea) S Sungjin Cho (Department of Chemistry Pohang University of Science and Technology (POSTECH) Pohang 37673 Republic of Korea) Y Yeong Kwon Kim (School of Electronic and Electrical Engineering Kyungpook National University Daegu Republic of Korea) E Eun Bee Ko (School of Materials Science and Engineering Kumoh National Institute of Technology Gumi 39177 Republic of Korea) S Seon Yeon Choi J Jung A Heo (School of Materials Science and Engineering Kumoh National Institute of Technology Gumi 39177 Republic of Korea) D Daegun Kim (School of Chemical Biological and Battery Engineering Gachon University Seongnam 13120 Republic of Korea) H Hocheon Yoo S So‐Yeon Lee (School of Materials Science and Engineering Kumoh National Institute of Technology Gumi 39177 Republic of Korea) Y YongJoo Kim (Department of Materials Science and Engineering) P Pil‐Ryung Cha (School of Materials Science and Engineering Kookmin University Seoul 02707 Republic of Korea) D Dong Yun Lee S Sunghun Lee (Division of Nanotechnology Convergence Research Institute Daegu Gyeongbuk Institute of Science and Technology Daegu 42988 Republic of Korea) B Byung Chul Jang (School of Electronic and Electrical Engineering Kyungpook National University Daegu Republic of Korea) Y Yeonhoo Kim H Hyun Ho Kim

Abstract

AbstractNanostructured transition metal oxides (NTMOs) have consistently piqued scientific interest for several decades due to their remarkable versatility across various fields. More recently, they have gained significant attention as materials employed for energy storage/harvesting devices as well as electronic devices. However, mass production of high‐quality NTMOs in a well‐controlled manner still remains challenging. Here, a universal, ultrafast, and solvent‐free method is presented for producing highly crystalline NTMOs directly onto target substrates. The findings reveal that the growth mechanism involves the solidification of condensed liquid‐phase TMO microdroplets onto the substrate under an oxygen‐rich ambient condition. This enables a continuous process under ambient air conditions, allowing for processing within just a few tens of seconds per sample. Finally, it is confirmed that the method can be extended to the synthesis of various NTMOs and their related compounds.

Article Details

Volume / Issue Vol. 37, Issue 16
Published April 01, 2025
ISSN 0935-9648
Publisher Unknown Publisher

Journal Info

Advanced Materials

Unknown Publisher

ISSN: 0935-9648 Physical Sciences

Authors (17)

S

Si Heon Lim

G

Geunwoo Kim

Department of Materials Science and Engineering Korea University Seoul 02841 Republic of Korea

S

Sungjin Cho

Department of Chemistry Pohang University of Science and Technology (POSTECH) Pohang 37673 Republic of Korea

Y

Yeong Kwon Kim

School of Electronic and Electrical Engineering Kyungpook National University Daegu Republic of Korea

E

Eun Bee Ko

School of Materials Science and Engineering Kumoh National Institute of Technology Gumi 39177 Republic of Korea

S

Seon Yeon Choi

J

Jung A Heo

School of Materials Science and Engineering Kumoh National Institute of Technology Gumi 39177 Republic of Korea

D

Daegun Kim

School of Chemical Biological and Battery Engineering Gachon University Seongnam 13120 Republic of Korea

H

Hocheon Yoo

S

So‐Yeon Lee

School of Materials Science and Engineering Kumoh National Institute of Technology Gumi 39177 Republic of Korea

Y

YongJoo Kim

Department of Materials Science and Engineering

P

Pil‐Ryung Cha

School of Materials Science and Engineering Kookmin University Seoul 02707 Republic of Korea

D

Dong Yun Lee

S

Sunghun Lee

Division of Nanotechnology Convergence Research Institute Daegu Gyeongbuk Institute of Science and Technology Daegu 42988 Republic of Korea

B

Byung Chul Jang

School of Electronic and Electrical Engineering Kyungpook National University Daegu Republic of Korea

Y

Yeonhoo Kim

H

Hyun Ho Kim