Tubular Nanostructures from Large‐Pore 2D Covalent Organic Frameworks
Abstract
AbstractThe synthesis of a wavy mesoporous 2D covalent organic framework (COF) with a 6‐nm hexagonal pore lattice (Joa‐COF‐1) is reported. This has been achieved by the synthesis of a terpyrenyl linker of approximately 2.7 nm in length and its subsequent condensation with a 3‐connected non‐planar cata‐hexabenzocoronene. Joa‐COF‐1 exists as non‐covalent tubular domains composed of π‐stacked 4 to 5 pores in 2D COF sections that can be separated by mild sonication, resulting in a family of tubular COF nanostructures that combine a 1D morphology with accessible mesopores.
Article Details
Authors (9)
Joaquín Almarza
POLYMAT University of the Basque Country UPV/EHU Avenida de Tolosa 72 Donostia‐San Sebastián 20018 Spain
Ian Cardillo‐Zallo
School of Chemistry University of Nottingham University Park Nottingham NG7 2RD UK
Karol Strutyński
CICECO−Aveiro Institute of Materials, Department of Chemistry
Marta Martínez‐Abadía
POLYMAT University of the Basque Country UPV/EHU Avenida de Tolosa 72 Donostia‐San Sebastián 20018 Spain
Natalia M. Padial
Functional Inorganic Materials Team, Instituto de Ciencia Molecular (ICMol)
Carlos Martí‐Gastaldo
Instituto de Ciencia Molecular Universidad de Valencia Paterna 46980 Spain
Manuel Melle‐Franco
Department of Chemistry, CICECO‐Aveiro Institute of Materials University of Aveiro Aveiro Portugal
Andrei N. Khlobystov
School of Chemistry
Aurelio Mateo‐Alonso
POLYMAT, Department of Applied Chemistry University of Basque Country (EHU) Donostia‐San Sebastián Spain