Transition path and interface sampling of stochastic Schrödinger dynamics

R Robson Christie (Department of Mathematics, Imperial College London 1 , London,) P Peter G. Bolhuis (van ’t Hoff Institute for Molecular Sciences) D David T. Limmer

Abstract

We study rare transitions in Markovian open quantum systems driven with Gaussian noise, applying transition path and interface sampling methods to trajectories generated by stochastic Schrödinger dynamics. Interface and path sampling offer insights into rare event transition mechanisms while simultaneously establishing a quantitative measure of the associated rate constant. Here, we extend their domain to systems described by stochastic Schrödinger equations. As a specific example, we explore a model of quantum Brownian motion in a quartic double well, consisting of a particle coupled to a Caldeira–Leggett oscillator bath, where we note significant departures from the Arrhenius law at low temperatures due to the presence of an anti-Zeno effect.

Article Details

Volume / Issue Vol. 162, Issue 11
Published March 21, 2025
ISSN 0021-9606
Publisher American Institute of Physics

Journal Info

The Journal of Chemical Physics

American Institute of Physics

ISSN: 0021-9606 Physical Sciences

Authors (3)

R

Robson Christie

Department of Mathematics, Imperial College London 1 , London,

P

Peter G. Bolhuis

van ’t Hoff Institute for Molecular Sciences

D

David T. Limmer