Toward electron self-localization in H2 gas: Multiple scattering effects on the electron drift mobility at low temperature and intermediate densities

A A. F. Borghesani (Dipartimento di Fisica ed Astronomia, Università degli Studi 1 , Padova,) G G. Carugno (Istituto Nazionale di Fisica Nucleare, Sez. Padova 2 , Padova,) G G. Messineo (Istituto Nazionale di Fisica Nucleare, Sez. Padova 2 , Padova,) J J. Pazzini

Abstract

We report here the first measurements of the electron drift mobility μ in gaseous H2 in the intermediate density range 0.5 × 1026 m−3 ≤ N ≤ 5 × 1026 m−3, at low temperature, T = 49.7 K and T = 29.7 K. In this range, the density is small enough to make the presence of electron states self-localized in bubbles negligible but, at the same time, is large enough for multiple scattering effects to alter the prediction of the classical kinetic theory for the mobility of quasi-free electrons. The analysis of the present data confirms the validity of the model we have developed to describe the quasi-free electron mobility in dense noble gases, which is based on the heuristic inclusion of multiple scattering effects in the classical kinetic theory.

Article Details

Volume / Issue Vol. 163, Issue 10
Published September 14, 2025
ISSN 0021-9606
Publisher American Institute of Physics

Journal Info

The Journal of Chemical Physics

American Institute of Physics

ISSN: 0021-9606 Physical Sciences

Authors (4)

A

A. F. Borghesani

Dipartimento di Fisica ed Astronomia, Università degli Studi 1 , Padova,

G

G. Carugno

Istituto Nazionale di Fisica Nucleare, Sez. Padova 2 , Padova,

G

G. Messineo

Istituto Nazionale di Fisica Nucleare, Sez. Padova 2 , Padova,

J

J. Pazzini