Synergistic Supramolecular Activation and Dynamic Alkalinity Replenishing for Sustainable Recycling of Ester‐Containing Plastics
Abstract
ABSTRACT Although alkaline hydrolysis represents a promising strategy for recycling polyester plastics, its practical deployment is hampered by the alkaline paradox: the excessive alkaline solution is required to sustain reaction kinetics, while it leads to severe equipment corrosion and wastewater burdens. Here we demonstrate a solvent‐induced alkaline self‐replenishing strategy that enables efficient recycling of diverse ester‐containing plastics, including thermosets (e.g., unsaturated polyester resin, epoxy resin, vinyl ester resin) and thermoplastics (e.g., PET, PBAT) under remarkably mild conditions. By exploiting the temperature‐dependent solubility of KOH in 1,3‐dimethyl‐2‐imidazolidinone (DMI), we established a dynamic alkaline balance: low solubility at room temperature confines it largely to the solid phase, whereas heating promotes dissolution that replenishes consumed base and prevents kinetic stagnation. Characterization evidence reveals that DMI acts as a molecular co‐activator, forming supramolecular complexes with K + to enhance OH − nucleophilicity and polarize ester bonds simultaneously. This system allows for the easy recovery of KOH via auto‐precipitation upon cooling, ensuring excellent reusability. Our work offers a universal and cost‐efficient dynamic methodological framework for the sustainable recycling of diverse polymer architectures.
Article Details
Authors (11)
Jun‐Yan Li
Collaborative Innovation Center for Eco‐Friendly and Fire‐Safety Polymeric Materials (MoE) National Key Laboratory of Advanced Polymer Materials Engineering National Engineering Laboratory of Eco‐Friendly Polymeric Materials (Sichuan) College of Chemistry Sichuan University Chengdu China
Xuehui Liu
Wenli An
Collaborative Innovation Center for Eco‐Friendly and Fire‐Safety Polymeric Materials (MoE) National Key Laboratory of Advanced Polymer Materials Engineering National Engineering Laboratory of Eco‐Friendly Polymeric Materials (Sichuan) College of Chemistry Sichuan University Chengdu China
Lei Yan
Department of Materials Science and Engineering
Yingqi Kong
Collaborative Innovation Center for Eco‐Friendly and Fire‐Safety Polymeric Materials (MoE) National Key Laboratory of Advanced Polymer Materials Engineering National Engineering Laboratory of Eco‐Friendly Polymeric Materials (Sichuan) College of Chemistry Sichuan University Chengdu China
Aiqin Huang
Key Laboratory of Green Chemistry and Technology College of Chemistry Ministry of Education Sichuan University Chengdu China
Li Hu
State Key Laboratory of Cognitive Science and Mental Health, Institute of Psychology, Chinese Academy of Sciences
Shumin Li
School of Earth Sciences and Engineering, Guangdong Provincial Key Lab of Geological Processes and Mineral Resources, Sun Yat-sen University
Zhishan Su
Shimei Xu
Collaborative Innovation Center for Eco‐Friendly and Fire‐Safety Polymeric Materials (MoE) National Key Laboratory of Advanced Polymer Materials Engineering National Engineering Laboratory of Eco‐Friendly Polymeric Materials (Sichuan) College of Chemistry Sichuan University Chengdu China
Yu‐Zhong Wang
Collaborative Innovation Center for Eco‐Friendly and Fire‐Safety Polymeric Materials (MoE) National Key Laboratory of Advanced Polymer Materials Engineering National Engineering Laboratory of Eco‐Friendly Polymeric Materials (Sichuan) College of Chemistry Sichuan University Chengdu China