Substantial reductions in black carbon from both fossil fuels and biomass burning during China’s Clean Air Action

J Junwen Liu (Institute for Environmental and Climate Research, College of Environment and Climate, Jinan University) F Fan Jiang (State Key Laboratory of Advanced Environmental Technology, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences) Q Qiongqiong Wang (Division of Environment and Sustainability, Hong Kong University of Science and Technology) G Gan Zhang J Jun Li W Weihua Chen P Ping Ding (State Key Laboratory of Deep Earth Processes and Resources, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences) S Sanyuan Zhu (State Key Laboratory of Advanced Environmental Technology, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences) Z Zhineng Cheng (State Key Laboratory of Advanced Environmental Technology, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences) X Xiangyun Zhang (State Key Laboratory of Advanced Environmental Technology, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences) Q Qinge Sha (Institute for Environmental and Climate Research, College of Environment and Climate, Jinan University) Z Zhijiong Huang (Institute for Environmental and Climate Research, College of Environment and Climate, Jinan University) X Xin Yuan J Junyu Zheng (Sustainable Energy and Environment Thrust, Hong Kong University of Science and Technology) Y Yanlin Zhang (School of Materials Science and Engineering, Zhejiang University) C Caiqing Yan (Environment Research Institute, Shandong University) C Chongguo Tian (CAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences) Y Yingjun Chen (Research Center for Analytical Sciences, Frontiers Science Center for New Organic Matter, and Key Laboratory of Biosensing and Molecular Recognition, College of Chemistry) J Jian Zhen Yu (Division of Environment and Sustainability, Hong Kong University of Science and Technology) Örjan Gustafsson (Department of Environmental Science and the Bolin Centre for Climate Research, Stockholm University)

Abstract

Black carbon (BC) aerosols exacerbate air pollution and climate warming, but their climatic impacts and sources are poorly constrained by bottom–up emission inventories (EIs). China’s Clean Air Action (CAA), which was launched in 2013, provides an excellent opportunity for investigating interannual variations in source contributions and validate the accuracy of EIs. Here, we present an 11-y (2008–2018) record of the BC concentration and its source-diagnostic radiocarbon ( 14 C) and stable carbon isotope ( 13 C) signatures at a receptor site in the Pearl River Delta (PRD) region, South China. The results revealed that the implementation of the CAA (2014–2018) led to a 41% reduction in the BC concentration compared with that in the preaction period (2008–2013). There is a large and systemic discrepancy over the whole period in the contribution of biomass burning to BC in South China between predictions from technology-based EIs (4 to 9%) and these source-diagnostic dual-isotopic fingerprints of actual ambient aerosols (21 to 32%). Observational constraints by source-diagnostic δ 13 C/Δ 14 C isotope measurements revealed that the reduction in biomass burning contributed 22% to the decrease in BC associated with the CAA, whereas predictions from EIs assigned a much smaller fraction. These results emphasize the need for observation-based source diagnostics of changing BC emission sources. Detailed source apportionment using independent δ 13 C/Δ 14 C isotope methodology is crucial for refining air pollution control strategies and improving the accuracy of models used for assessing the air quality and climate effects of BC in China and elsewhere.

Article Details

Volume / Issue Vol. 122, Issue 35
Published September 02, 2025
ISSN 0027-8424
Publisher National Academy of Sciences

Authors (20)

J

Junwen Liu

Institute for Environmental and Climate Research, College of Environment and Climate, Jinan University

F

Fan Jiang

State Key Laboratory of Advanced Environmental Technology, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences

Q

Qiongqiong Wang

Division of Environment and Sustainability, Hong Kong University of Science and Technology

G

Gan Zhang

J

Jun Li

W

Weihua Chen

P

Ping Ding

State Key Laboratory of Deep Earth Processes and Resources, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences

S

Sanyuan Zhu

State Key Laboratory of Advanced Environmental Technology, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences

Z

Zhineng Cheng

State Key Laboratory of Advanced Environmental Technology, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences

X

Xiangyun Zhang

State Key Laboratory of Advanced Environmental Technology, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences

Q

Qinge Sha

Institute for Environmental and Climate Research, College of Environment and Climate, Jinan University

Z

Zhijiong Huang

Institute for Environmental and Climate Research, College of Environment and Climate, Jinan University

X

Xin Yuan

J

Junyu Zheng

Sustainable Energy and Environment Thrust, Hong Kong University of Science and Technology

Y

Yanlin Zhang

School of Materials Science and Engineering, Zhejiang University

C

Caiqing Yan

Environment Research Institute, Shandong University

C

Chongguo Tian

CAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences

Y

Yingjun Chen

Research Center for Analytical Sciences, Frontiers Science Center for New Organic Matter, and Key Laboratory of Biosensing and Molecular Recognition, College of Chemistry

J

Jian Zhen Yu

Division of Environment and Sustainability, Hong Kong University of Science and Technology

Örjan Gustafsson

Department of Environmental Science and the Bolin Centre for Climate Research, Stockholm University