Spin Frustration and Unconventional Surface Spin Canting State in Van der Waals Ferromagnet/Antiferromagnet Heterostructures

T Tianye Wang Q Qian Li M Mengmeng Yang Y Yu Sun A Alpha T. N'Diaye (Advanced Light Source, Lawrence Berkeley National Laboratory 7 , Berkeley, California 94720,) C Christoph Klewe (Materials Sciences Division, Lawrence Berkeley National Laboratory) A Andreas Scholl X Xianzhe Chen X Xiaoxi Huang H Hongrui Zhang S Santai Yang (Department of Physics University of California Berkeley CA 94720 USA) J Ji‐Eun Lee (Department of Physics University of California Berkeley CA 94720 USA) D Dhanvanth Balakrishnan (Department of Physics University of California Berkeley CA 94720 USA) X Xixiang Zhang (Material Science and Engineering Program, Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, Kingdom of Saudi Arabia.) C Chanyong Hwang P Padraic C. Shafer (Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA) M Michael F. Crommie R Ramamoorthy Ramesh (Rice Advanced Materials Institute) Z Zi Q. Qiu (Department of Physics University of California Berkeley CA 94720 USA)

Abstract

Abstract Atomically flat surfaces of van der Waals (vdW) materials pave an avenue for addressing a long‐standing fundamental issue of how a compensated antiferromagnet (AFM) surface frustrates a ferromagnetic (FM) overlayer in FM/AFM heterostructures. We investigate Fe 5 GeTe 2 /NiPS 3 vdW heterostructures by characterizing AFM and FM spins separately. We find that in‐plane zig‐zag AFM NiPS 3 develops three equivalent AFM domains, which are robust against external magnetic field and magnetic coupling with Fe 5 GeTe 2 . Moreover, evidence is provided of in‐plane‐AFM‐induced perpendicular magnetic anisotropy (PMA) in adjacent Fe 5 GeTe 2 , and an unconventional out‐of‐plane surface spin canting state with the Fe 5 GeTe 2 spins spatially turn from out‐of‐plane direction near the interface to in‐plane direction away from the interface in Fe 5 GeTe 2 /NiPS 3 . The out‐of‐plane surface spin canting is a unique property of spin frustration in vdW magnetic heterostructures.

Article Details

Volume / Issue Vol. 37, Issue 42
Published October 01, 2025
ISSN 0935-9648
Publisher Unknown Publisher

Journal Info

Advanced Materials

Unknown Publisher

ISSN: 0935-9648 Physical Sciences

Authors (19)

T

Tianye Wang

Q

Qian Li

M

Mengmeng Yang

Y

Yu Sun

A

Alpha T. N'Diaye

Advanced Light Source, Lawrence Berkeley National Laboratory 7 , Berkeley, California 94720,

C

Christoph Klewe

Materials Sciences Division, Lawrence Berkeley National Laboratory

A

Andreas Scholl

X

Xianzhe Chen

X

Xiaoxi Huang

H

Hongrui Zhang

S

Santai Yang

Department of Physics University of California Berkeley CA 94720 USA

J

Ji‐Eun Lee

Department of Physics University of California Berkeley CA 94720 USA

D

Dhanvanth Balakrishnan

Department of Physics University of California Berkeley CA 94720 USA

X

Xixiang Zhang

Material Science and Engineering Program, Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, Kingdom of Saudi Arabia.

C

Chanyong Hwang

P

Padraic C. Shafer

Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA

M

Michael F. Crommie

R

Ramamoorthy Ramesh

Rice Advanced Materials Institute

Z

Zi Q. Qiu

Department of Physics University of California Berkeley CA 94720 USA