Singlet-Oxygen-Driven C(sp
                    <sup>2</sup>
                    )–P Bond Cleavage Enables Red-Light Uncaging of Phosphorus(V) Prodrugs on Gold Nanoclusters

Kenji Watanabe; Ikuru Takada; Riko Yamamoto; Hiroto Kobashi; Kotaro Maki; Natsumi Nomura; Rio Sasada; Iuchi Tai; Hideyasu China; Takashi Niwa; Takamitsu Hosoya; Hiroaki Kitagishi; Shigeru Negi; Masahito Kodera; Yasutomo Yamamoto

doi:10.1021/jacs.6c00254

Journal of the American Chemical Society

Singlet-Oxygen-Driven C(sp <sup>2</sup> )–P Bond Cleavage Enables Red-Light Uncaging of Phosphorus(V) Prodrugs on Gold Nanoclusters

K Kenji Watanabe I Ikuru Takada (Faculty of Pharmaceutical Sciences) R Riko Yamamoto (Faculty of Science and Engineering) H Hiroto Kobashi (Faculty of Science and Engineering) K Kotaro Maki (Faculty of Science and Engineering) N Natsumi Nomura (Faculty of Pharmaceutical Sciences) R Rio Sasada (Faculty of Pharmaceutical Sciences) I Iuchi Tai (Faculty of Pharmaceutical Sciences) H Hideyasu China (Faculty of Pharmaceutical Sciences) T Takashi Niwa (Graduate School of Pharmaceutical Sciences, Kyusyu University, Higashi-ku, Fukuoka 812-8582, Japan) T Takamitsu Hosoya (Chemical Bioscience Team, Laboratory for Biomaterials and Bioengineering, Institute of Integrated Research, Institute of Science Tokyo, Chiyoda-ku, Tokyo 101-0062, Japan) H Hiroaki Kitagishi (Faculty of Science and Engineering) S Shigeru Negi (Faculty of Pharmaceutical Sciences) M Masahito Kodera (Faculty of Science and Engineering) Y Yasutomo Yamamoto (Faculty of Pharmaceutical Sciences)

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Article Details

Journal Journal of the American Chemical Society

Volume / Issue Vol. 148, Issue 15

Published April 22, 2026

Pages 16039-16048

DOI 10.1021/jacs.6c00254

ISSN 0002-7863

Publisher American Chemical Society

Journal Info

Journal of the American Chemical Society

American Chemical Society

ISSN: 0002-7863 Physical Sciences

Authors (15)

K

Kenji Watanabe

I

Ikuru Takada

Faculty of Pharmaceutical Sciences

R

Riko Yamamoto

Faculty of Science and Engineering

H

Hiroto Kobashi

Faculty of Science and Engineering

K

Kotaro Maki

Faculty of Science and Engineering

N

Natsumi Nomura

Faculty of Pharmaceutical Sciences

R

Rio Sasada

Faculty of Pharmaceutical Sciences

I

Iuchi Tai

Faculty of Pharmaceutical Sciences

H

Hideyasu China

Faculty of Pharmaceutical Sciences

T

Takashi Niwa

Graduate School of Pharmaceutical Sciences, Kyusyu University, Higashi-ku, Fukuoka 812-8582, Japan

T

Takamitsu Hosoya

Chemical Bioscience Team, Laboratory for Biomaterials and Bioengineering, Institute of Integrated Research, Institute of Science Tokyo, Chiyoda-ku, Tokyo 101-0062, Japan

H

Hiroaki Kitagishi

Faculty of Science and Engineering

S

Shigeru Negi

Faculty of Pharmaceutical Sciences

M

Masahito Kodera

Faculty of Science and Engineering

Y

Yasutomo Yamamoto

Faculty of Pharmaceutical Sciences

Singlet-Oxygen-Driven C(sp <sup>2</sup> )–P Bond Cleavage Enables Red-Light Uncaging of Phosphorus(V) Prodrugs on Gold Nanoclusters

Article Details

Journal Info

Authors (15)

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