Simulating quantum circuit expectation values by Clifford perturbation theory

T Tomislav Begušić (Institute of Physical and Theoretical Chemistry, University of Würzburg 2 , 97074 Würzburg,) K Kasra Hejazi (Division of Chemistry and Chemical Engineering, California Institute of Technology , Pasadena, California 91125,) G Garnet Kin-Lic Chan (Division of Chemistry and Chemical Engineering)

Abstract

The classical simulation of quantum circuits is of central importance for benchmarking near-term quantum devices. The fact that gates belonging to the Clifford group can be simulated efficiently on classical computers has motivated a range of methods that scale exponentially only in the number of non-Clifford gates. Here, we consider the expectation value problem for circuits composed of Clifford gates and non-Clifford Pauli rotations and introduce a heuristic perturbative approach based on the truncation of the exponentially growing sum of Pauli terms in the Heisenberg picture. Numerical results are shown on a quantum approximate optimization algorithm benchmark for the E3LIN2 problem, and we also demonstrate how this method can be used to quantify coherent and incoherent errors of local observables in Clifford circuits. Our results indicate that this systematically improvable perturbative method offers a viable alternative to exact methods for approximating expectation values of large near-Clifford circuits.

Article Details

Volume / Issue Vol. 162, Issue 15
Published April 21, 2025
ISSN 0021-9606
Publisher American Institute of Physics

Journal Info

The Journal of Chemical Physics

American Institute of Physics

ISSN: 0021-9606 Physical Sciences

Authors (3)

T

Tomislav Begušić

Institute of Physical and Theoretical Chemistry, University of Würzburg 2 , 97074 Würzburg,

K

Kasra Hejazi

Division of Chemistry and Chemical Engineering, California Institute of Technology , Pasadena, California 91125,

G

Garnet Kin-Lic Chan

Division of Chemistry and Chemical Engineering