Scaling Up Purcell‐Enhanced Self‐Assembled Nanoplasmonic Perovskite Scintillators into the Bulk Regime

M Michal Makowski (Lukasiewicz Research Network ‐ PORT Polish Center for Technology Development Wroclaw 54‐066 Poland) W Wenzheng Ye (CINTRA (CNRS‐International‐NTU‐THALES Research Alliance) IRL 3288 Research Techno Plaza 50 Nanyang Drive, Border X Block, Level 6 Singapore 637553 Singapore) D Dominik Kowal F Francesco Maddalena (CINTRA (CNRS‐International‐NTU‐THALES Research Alliance) IRL 3288 Research Techno Plaza 50 Nanyang Drive, Border X Block, Level 6 Singapore 637553 Singapore) S Somnath Mahato (Łukasiewicz Research Network – PORT Polish Centre for Technology Development Stabłowicka 147 Wrocław 54‐066 Poland) Y Yudhistira Tirtayasri Amrillah (Department of Physics, Faculty of Mathematics and Natural Sciences Universitas Indonesia Depok 16424 Indonesia) W Weronika Zajac (Lukasiewicz Research Network ‐ PORT Polish Center for Technology Development Wroclaw 54‐066 Poland) M Marcin Eugeniusz Witkowski (Institute of Physics, Faculty of Physics, Astronomy, and Informatics Nicolaus Copernicus University in Torun Torun 87‐100 Poland) K Konrad Jacek Drozdowski (Institute of Physics, Faculty of Physics, Astronomy, and Informatics Nicolaus Copernicus University in Torun Torun 87‐100 Poland) N Nathaniel (Department of Physics, Faculty of Mathematics and Natural Sciences Universitas Indonesia Depok 16424 Indonesia) C Cuong Dang J Joanna Cybinska (Lukasiewicz Research Network ‐ PORT Polish Center for Technology Development Wroclaw 54‐066 Poland) W Winicjusz Drozdowski (Faculty of Physics, Astronomy and Informatics Institute of Physics Nicolaus Copernicus University in Toruń Toruń Poland) F Ferry Anggoro Ardy Nugroho (Department of Physics, Faculty of Mathematics and Natural Sciences Universitas Indonesia Depok 16424 Indonesia) C Christophe Dujardin (Universite Claude Bernard Lyon 1 Institut Lumiere Matiere UMR 5306 CNRS 10 rue Ada Byron Villeurbanne 69622 France) L Liang Jie Wong M Muhammad Danang Birowosuto

Abstract

AbstractScintillators convert high‐energy radiation into detectable photons and play a crucial role in medical imaging and security applications. The enhancement of scintillator performance through nanophotonics and nanoplasmonics, specifically using the Purcell effect, has shown promise but has so far been limited to ultrathin scintillator films because of the localized nature of this effect. This study introduces a method to expand the application of nanoplasmonic scintillators to the bulk regime. By integrating 100‐nm‐sized plasmonic spheroid and cuboid nanoparticles with perovskite scintillator nanocrystals, nanoplasmonic scintillators are enabled to function effectively within bulk‐scale devices. Power and decay rate enhancements of up to (3.20 ± 0.20) and (4.20 ± 0.31) folds are experimentally demonstrated for plasmonic spheroid and cuboid nanoparticles, respectively, in a 5‐mm thick CsPbBr3 nanocrystal‐polymer scintillator at RT. Theoretical modeling also predicts similar enhancements of up to (2.26 ± 0.31) and (3.02 ± 0.69) folds for the same nanoparticle shapes and dimensions. Moreover, a (2.07 ± 0.39) fold increase in light yield under 241Am γ‐excitation is demonstrated. These findings provide a viable pathway for utilizing nanoplasmonics to enhance bulk scintillator devices, advancing radiation detection technology.

Article Details

Volume / Issue Vol. 37, Issue 30
Published July 01, 2025
ISSN 0935-9648
Publisher Unknown Publisher

Journal Info

Advanced Materials

Unknown Publisher

ISSN: 0935-9648 Physical Sciences

Authors (17)

M

Michal Makowski

Lukasiewicz Research Network ‐ PORT Polish Center for Technology Development Wroclaw 54‐066 Poland

W

Wenzheng Ye

CINTRA (CNRS‐International‐NTU‐THALES Research Alliance) IRL 3288 Research Techno Plaza 50 Nanyang Drive, Border X Block, Level 6 Singapore 637553 Singapore

D

Dominik Kowal

F

Francesco Maddalena

CINTRA (CNRS‐International‐NTU‐THALES Research Alliance) IRL 3288 Research Techno Plaza 50 Nanyang Drive, Border X Block, Level 6 Singapore 637553 Singapore

S

Somnath Mahato

Łukasiewicz Research Network – PORT Polish Centre for Technology Development Stabłowicka 147 Wrocław 54‐066 Poland

Y

Yudhistira Tirtayasri Amrillah

Department of Physics, Faculty of Mathematics and Natural Sciences Universitas Indonesia Depok 16424 Indonesia

W

Weronika Zajac

Lukasiewicz Research Network ‐ PORT Polish Center for Technology Development Wroclaw 54‐066 Poland

M

Marcin Eugeniusz Witkowski

Institute of Physics, Faculty of Physics, Astronomy, and Informatics Nicolaus Copernicus University in Torun Torun 87‐100 Poland

K

Konrad Jacek Drozdowski

Institute of Physics, Faculty of Physics, Astronomy, and Informatics Nicolaus Copernicus University in Torun Torun 87‐100 Poland

N

Nathaniel

Department of Physics, Faculty of Mathematics and Natural Sciences Universitas Indonesia Depok 16424 Indonesia

C

Cuong Dang

J

Joanna Cybinska

Lukasiewicz Research Network ‐ PORT Polish Center for Technology Development Wroclaw 54‐066 Poland

W

Winicjusz Drozdowski

Faculty of Physics, Astronomy and Informatics Institute of Physics Nicolaus Copernicus University in Toruń Toruń Poland

F

Ferry Anggoro Ardy Nugroho

Department of Physics, Faculty of Mathematics and Natural Sciences Universitas Indonesia Depok 16424 Indonesia

C

Christophe Dujardin

Universite Claude Bernard Lyon 1 Institut Lumiere Matiere UMR 5306 CNRS 10 rue Ada Byron Villeurbanne 69622 France

L

Liang Jie Wong

M

Muhammad Danang Birowosuto