Region-specific defect engineering of Bi2W1-xO6-γ induces nanoscale electric fields and surface active-sites for enhanced visible-light oxidation of salt-lake flotation agents

Abstract

Abstract Breaking the limitations of conventional defect engineering, this work pioneers region-specific dual-defect engineering in Bi 2 WO 6 . By precisely tailoring tungsten (W) and oxygen (O) vacancies at nanoscale spatial domains-W vacancies at the edges and O vacancies at the center-a spatially asymmetric defect configuration is achieved. This configuration induces a synergistic “defect dipole” effect, amplifying the internal electric field by 2.74 times while simultaneously enriching surface-active sites. As a result, the photocatalytic efficiency is dramatically enhanced, achieving complete oxidation of recalcitrant flotation agents-octadecylamine (ODA) and 4-dodecylmorpholine (DMP)-within just 2 h of visible light irradiation, which is 3.6 times faster than that of pristine Bi 2 WO 6 . Additionally, the generation of reactive species ( $$\cdot {{\rm{O}}}_{2}^{-}$$ ⋅ O 2 − , $${}^{1}{\rm{O}}_{2}$$ O 2 1 , and h⁺) is significantly boosted by factors of 8.98, 5.55, and 20.02, respectively, highlighting the material’s remarkable reactivity. Photoelectrochemical analyses reveal a remarkable 290% increase in charge separation efficiency. This enhancement is further supported by an improved O 2 adsorption capacity, which promotes the formation of reactive oxygen species involved in the degradation process. Impressively, the engineered Bi₂W₁₋ₓO₆₋ᵧ exhibits outstanding performance in real-world industrial wastewater treatment under solar irradiation, demonstrating its practical viability. Overall, this work establishes a new paradigm in photocatalysis by integrating precise nanoscale defect engineering with enhanced electrostatic modulation.