Reactive Carbide‐Based Synthesis and Microstructure of NASICON Sodium Metal All Solid‐State Electrolyte

Abstract

Abstract Reactive carbide precursor‐based synthesis of NASICON‐type NZSP (Na 1+x Zr 2 Si x P 3‐x O 12 ) solid‐state electrolyte (SSE) is demonstrated, in contrast to the established oxide‐based approach. Exothermic decomposition of ZrC and SiC in air homogenizes microstructure, yielding 98% compact density after conventional sintering at 1200 °C. Quantitative stereology demonstrates that significant microstructural differences are present. Compacts of carbide‐derived Carb‐NZSP are 98% dense with a secondary zirconium oxide (ZrO 2 ) volume fraction of 0.2% ± 0.3%, versus 93% dense and 3% ± 1% for oxide‐derived baseline. For Carb‐NZSP, the secondary glassy phosphate phase is agglomerated, while for baseline, it is dispersed and percolated. Electrochemical testing combined with post‐mortem analysis demonstrates how microstructural control of secondary phases is critical for dendrite suppression: Carb‐NZSP critical current density (CCD) is 3.1 ± 0.8 mA cm − 2 at 0.1 mAh cm − 2 , versus 1.0 ± 0.7 mA cm −2 at 0.1 mAh cm −2 . Cryogenic focused ion beam (cryo‐FIB) analysis demonstrates that in both materials, the porous 2D sheet‐like sodium metal dendrites propagate around and subsume NZSP grains, likely following a path enriched with glassy phase and with porosity. Dendrites also flow around isolated zirconia particles. Phase field simulation reveals deflection of dendrites by mechanically tough zirconia, while brittle glassy phase accelerates dendrite growth, especially when finely distributed.