Radical Propagation via σ-Cleavage Mediates Radical SAM Catalyzed Sulfur-for-Oxygen Swapping Reaction during the Biosynthesis of Albomycin δ<sub>2</sub>

Z Ziyang Zheng (Department of Chemistry) R Richiro Ushimaru (Institute for Advanced Study and Department of Chemistry, Graduate School of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan) C Conor M. Thomas (Department of Chemistry) H Hung-wen Liu

Article Details

Volume / Issue Vol. 147, Issue 35
Published September 03, 2025
Pages 32118-32123
ISSN 0002-7863
Publisher American Chemical Society

Journal Info

Journal of the American Chemical Society

American Chemical Society

ISSN: 0002-7863 Physical Sciences

Authors (4)

Z

Ziyang Zheng

Department of Chemistry

R

Richiro Ushimaru

Institute for Advanced Study and Department of Chemistry, Graduate School of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

C

Conor M. Thomas

Department of Chemistry

H

Hung-wen Liu