Quantum trajectories and reduced dynamics in time-correlated environments

Abstract

The stochastic Schrödinger equation (SSE) provides a trajectory-level route to simulate the dynamics of open quantum systems with applications ranging from molecular processes to quantum technologies. We study a colored-noise extension of the SSE based on an Ornstein–Uhlenbeck (OU) noise drive and benchmark its ensemble-averaged dynamics against the standard white-noise SSE and against a fluctuating OU random Hamiltonian. When the environment exhibits a finite correlation time, averaging over pure-state trajectories yields master equations that are generally open-form and not of Lindblad type, yet remain positive by construction. By considering the differential of the OU process, we define an effective correlated noise, whose properties we analyze and use to formulate an SSE unraveling of its associated open-form quantum master equation. We show that the averaged dissipator separates into a Lindblad contribution stemming from the white-noise component and additional correlation terms arising from the fluctuations of the OU Hamiltonian. To obtain a practical closed description and physical intuition, we introduce a Redfield-inspired perturbative closure for these correlation terms, providing an effective master equation for the colored SSE. For a two-level system, the resulting dynamics exhibit long-lived coherences, nontrivial stationary (including oscillatory) states, and multi-timescale relaxation, rationalized through the components of a time-dependent Redfield tensor.