Plastics of the Future? An Interdisciplinary Review on Biobased and Biodegradable Polymers: Progress in Chemistry, Societal Views, and Environmental Implications

S Sara T. R. Velasquez (Sustainable Polymer Chemistry (SPC), Department of Molecules and Materials MESA+ Institute for Nanotechnology Faculty of Science and Technology University of Twente P.O. Box 217, 7500 AE Enschede Netherlands) Q Qisong Hu (Sustainable Polymer Chemistry (SPC), Department of Molecules and Materials MESA+ Institute for Nanotechnology Faculty of Science and Technology University of Twente P.O. Box 217, 7500 AE Enschede Netherlands) J Johanna Kramm (Institute for Social‐Ecological Research (ISOE) Hamburger Allee 45 60486 Frankfurt am Main Germany) V Vitória C. Santin (Sustainable Polymer Chemistry (SPC), Department of Molecules and Materials MESA+ Institute for Nanotechnology Faculty of Science and Technology University of Twente P.O. Box 217, 7500 AE Enschede Netherlands) C Carolin Völker (Institute for Social‐Ecological Research (ISOE) Hamburger Allee 45 60486 Frankfurt am Main Germany) F Frederik R. Wurm (Sustainable Polymer Chemistry (SPC), Department of Molecules and Materials MESA+ Institute for Nanotechnology Faculty of Science and Technology University of Twente P.O. Box 217, 7500 AE Enschede Netherlands)

Abstract

AbstractGlobal demand to reduce polymer waste and microplastics pollution has increased in recent years, prompting further research, development, and wider use of biodegradable and biobased polymers (BBPs). BBPs have emerged as promising alternatives to conventional plastics, with the potential to mitigate the environmental burdens of persistent plastic waste. We provide an updated perspective on their impact, five years after our last article, featuring several recent advances, particularly in exploring broader variety of feedstock, applying novel chemical modifications, and developing new functionalities. Life‐cycle assessments reveal that environmental performance of BBPs depends on several factors including feedstock selection, production efficiency, and end‐of‐life management. Furthermore, the introduction of BBPs in several everyday life products has also influenced consumer perception, market dynamics, and regulatory frameworks. Although offering environmental advantages in specific applications, BBPs also raise concerns regarding their biodegradability under varying environmental conditions, potential microplastic generation, and soil health impacts. We highlight the need for a circular approach considering the entire polymer life cycle, from feedstock sourcing, modification and use, to end‐of‐life options. Interdisciplinary research, collaborative initiatives, and informed policymaking are crucial to unlocking the full potential of BBPs and exploiting their contribution to create a circular economy and more sustainable future.

Article Details

Volume / Issue Vol. 64, Issue 23
Published June 02, 2025
ISSN 1433-7851
Publisher Wiley

Journal Info

Angewandte Chemie International Edition

Wiley

ISSN: 1433-7851 Physical Sciences

Authors (6)

S

Sara T. R. Velasquez

Sustainable Polymer Chemistry (SPC), Department of Molecules and Materials MESA+ Institute for Nanotechnology Faculty of Science and Technology University of Twente P.O. Box 217, 7500 AE Enschede Netherlands

Q

Qisong Hu

Sustainable Polymer Chemistry (SPC), Department of Molecules and Materials MESA+ Institute for Nanotechnology Faculty of Science and Technology University of Twente P.O. Box 217, 7500 AE Enschede Netherlands

J

Johanna Kramm

Institute for Social‐Ecological Research (ISOE) Hamburger Allee 45 60486 Frankfurt am Main Germany

V

Vitória C. Santin

Sustainable Polymer Chemistry (SPC), Department of Molecules and Materials MESA+ Institute for Nanotechnology Faculty of Science and Technology University of Twente P.O. Box 217, 7500 AE Enschede Netherlands

C

Carolin Völker

Institute for Social‐Ecological Research (ISOE) Hamburger Allee 45 60486 Frankfurt am Main Germany

F

Frederik R. Wurm

Sustainable Polymer Chemistry (SPC), Department of Molecules and Materials MESA+ Institute for Nanotechnology Faculty of Science and Technology University of Twente P.O. Box 217, 7500 AE Enschede Netherlands