Phase behavior of active particle-loaded vesicles

A A. D. Chen (Department of Chemistry, Columbia University , 3000 Broadway, New York, New York 10027,) A A. Cacciuto (Department of Chemistry, Columbia University , 3000 Broadway, New York, New York 10027,)

Abstract

We investigate the phase behavior of flexible two-dimensional vesicles loaded with self-avoiding active particles. We construct structural phase diagrams as a function of system density, particle loading, and the degree of activity of the particles inside the vesicle. We identify a range of non-trivial structures reminiscent of those observed in systems of liquid crystals. We examine the stability of these phases with varying particle load and activity, finding that while activity often destabilizes the ordered structures by exciting their soft modes, it can also induce novel ordered configurations absent in the parent passive system.

Article Details

Volume / Issue Vol. 163, Issue 23
Published December 21, 2025
ISSN 0021-9606
Publisher American Institute of Physics

Journal Info

The Journal of Chemical Physics

American Institute of Physics

ISSN: 0021-9606 Physical Sciences

Authors (2)

A

A. D. Chen

Department of Chemistry, Columbia University , 3000 Broadway, New York, New York 10027,

A

A. Cacciuto

Department of Chemistry, Columbia University , 3000 Broadway, New York, New York 10027,