Perspective: Time irreversibility in systems observed at coarse resolution

C Cai Dieball (Mathematical bioPhysics Group, Max Planck Institute for Multidisciplinary Sciences , 37077 Göttingen,) A Aljaž Godec (Mathematical bioPhysics Group, Max Planck Institute for Multidisciplinary Sciences , 37077 Göttingen,)

Abstract

A broken time-reversal symmetry, i.e., broken detailed balance, is central to non-equilibrium physics and is a prerequisite for life. However, it turns out to be quite challenging to unambiguously define and quantify time-reversal symmetry (and violations thereof) in practice, that is, from observations. Measurements on complex systems have a finite resolution and generally probe low-dimensional projections of the underlying dynamics, which are well known to introduce memory. In situations where many microscopic states become “lumped” onto the same observable “state” or when introducing “reaction coordinates” to reduce the dimensionality of data, signatures of a broken time-reversal symmetry in the microscopic dynamics become distorted or masked. In this Perspective, we highlight why, in defining and discussing time-reversal symmetry and quantifying its violations, the precise underlying assumptions on the microscopic dynamics, the coarse graining, and further reductions are not a technical detail. These assumptions decide whether the conclusions that are drawn are physically sound or inconsistent. We summarize recent findings in the field and reflect upon key challenges.

Article Details

Volume / Issue Vol. 162, Issue 9
Published March 07, 2025
ISSN 0021-9606
Publisher American Institute of Physics

Journal Info

The Journal of Chemical Physics

American Institute of Physics

ISSN: 0021-9606 Physical Sciences

Authors (2)

C

Cai Dieball

Mathematical bioPhysics Group, Max Planck Institute for Multidisciplinary Sciences , 37077 Göttingen,

A

Aljaž Godec

Mathematical bioPhysics Group, Max Planck Institute for Multidisciplinary Sciences , 37077 Göttingen,