Peptide-based covalent inhibitor of tubulin detyrosination promotes mesenchymal-to-epithelial transition in lung cancer cells

H Hathaichanok Impheng (Department of Physiology, Faculty of Medical Science, Naresuan University) G Ghislain Gillard (Tubulin Code team, Institute of Human Genetics, CNRS, Université Montpellier) N Nuttanid Numnoi (Department of Physiology, Faculty of Medical Science, Naresuan University) A Anthony Feral (IBMM (Institut des Biomolécules Max Mousseron), Amino Acids, Peptides and Proteins department, Université de Montpellier, CNRS, Ecole Nationale Supérieure de Chimie de Montpellier) M Matthieu Simon (IBMM (Institut des Biomolécules Max Mousseron), Amino Acids, Peptides and Proteins department, Université de Montpellier, CNRS, Ecole Nationale Supérieure de Chimie de Montpellier) M Maxime Louet (IBMM (Institut des Biomolécules Max Mousseron), Amino Acids, Peptides and Proteins department, Université de Montpellier, CNRS, Ecole Nationale Supérieure de Chimie de Montpellier) M Muriel Amblard (IBMM (Institut des Biomolécules Max Mousseron), Amino Acids, Peptides and Proteins department, Université de Montpellier, CNRS, Ecole Nationale Supérieure de Chimie de Montpellier) F François Juge (Tubulin Code Team, IGH (Institute of Human Genetics) UMR 9002, Genetics, Cell Biology and Development department, Univ Montpellier, CNRS) L Lubomir Vezenkov (IBMM (Institut des Biomolécules Max Mousseron), Amino Acids, Peptides and Proteins department, Université de Montpellier, CNRS, Ecole Nationale Supérieure de Chimie de Montpellier) K Krzysztof Rogowski (Tubulin Code team, Institute of Human Genetics, CNRS, Université Montpellier)

Abstract

Detyrosination is a reversible posttranslational modification specific to α-tubulin, which has been implicated in cancer progression and invasiveness by promoting epithelial-to-mesenchymal transition. The members of the vasohibin family, VASH1 and VASH2, were previously identified as the first class of enzymes involved in catalyzing this modification. Here, we report the development of a covalent VASH inhibitor, which is characterized by high specificity and low toxicity. By combining the use of a new compound with molecular approaches in lung cancer cell lines, we find that tubulin detyrosination plays an important role in the maintenance of mesenchymal properties. We show that in the absence of VASH activity, collective cell migration and 3D spheroid formation are severely compromised. Moreover, we demonstrate that the observed phenotypes are caused by the accumulation of the important epithelial marker E-cadherin with simultaneous reduction in mesenchymal markers N-cadherin and vimentin. Taken together, our study establishes tubulin detyrosination as a promising target for the future development of anticancer treatment.

Article Details

Volume / Issue Vol. 123, Issue 1
Published January 06, 2026
ISSN 0027-8424
Publisher National Academy of Sciences

Authors (10)

H

Hathaichanok Impheng

Department of Physiology, Faculty of Medical Science, Naresuan University

G

Ghislain Gillard

Tubulin Code team, Institute of Human Genetics, CNRS, Université Montpellier

N

Nuttanid Numnoi

Department of Physiology, Faculty of Medical Science, Naresuan University

A

Anthony Feral

IBMM (Institut des Biomolécules Max Mousseron), Amino Acids, Peptides and Proteins department, Université de Montpellier, CNRS, Ecole Nationale Supérieure de Chimie de Montpellier

M

Matthieu Simon

IBMM (Institut des Biomolécules Max Mousseron), Amino Acids, Peptides and Proteins department, Université de Montpellier, CNRS, Ecole Nationale Supérieure de Chimie de Montpellier

M

Maxime Louet

IBMM (Institut des Biomolécules Max Mousseron), Amino Acids, Peptides and Proteins department, Université de Montpellier, CNRS, Ecole Nationale Supérieure de Chimie de Montpellier

M

Muriel Amblard

IBMM (Institut des Biomolécules Max Mousseron), Amino Acids, Peptides and Proteins department, Université de Montpellier, CNRS, Ecole Nationale Supérieure de Chimie de Montpellier

F

François Juge

Tubulin Code Team, IGH (Institute of Human Genetics) UMR 9002, Genetics, Cell Biology and Development department, Univ Montpellier, CNRS

L

Lubomir Vezenkov

IBMM (Institut des Biomolécules Max Mousseron), Amino Acids, Peptides and Proteins department, Université de Montpellier, CNRS, Ecole Nationale Supérieure de Chimie de Montpellier

K

Krzysztof Rogowski

Tubulin Code team, Institute of Human Genetics, CNRS, Université Montpellier