Molecular Ferroelectrics for Highly Sensitive Detection Toward Low‐Frequency Sound Recognition

R Ruonan Wang (State Key Laboratory of Common Mechanism Research for Major Diseases, Department of Biophysics and Structural Biology) L Lutao Li (School of Energy, School of Optoelectronic Science and Engineering, School of Physical Science and Technology) J Jiating Li (School of Energy School of Optoelectronic Science and Engineering School of Biology and Basic Medical Sciences School of Physical Science and Technology Soochow University Suzhou 215000 P. R. China) C Chen Wang S Shan Cong (School of Energy, School of Optoelectronic Science and Engineering, State Key Laboratory of Bioinspired Interfacial Materials Science, Institute of Functional Nano and Soft Materials Laboratory) G Guoxiang Zhao (State Key Laboratory of Structural Chemistry) X Xinyu Du C Chao‐Ran Huang (School of Energy School of Optoelectronic Science and Engineering School of Biology and Basic Medical Sciences School of Physical Science and Technology Soochow University Suzhou 215000 P. R. China) H Hengyu Cao (School of Energy, School of Optoelectronic Science and Engineering, School of Physical Science and Technology) W Weiyu Cheng (School of Energy, School of Optoelectronic Science and Engineering, State Key Laboratory of Bioinspired Interfacial Materials Science, Institute of Functional Nano and Soft Materials Laboratory) Y Yaqi Ye C Chengyuan Liu (National Synchrotron Radiation Laboratory) B Bin Li W Wei‐Qiang Liao (Ordered Matter Science Research Center Nanchang University Nanchang P. R. China) Z Zheng Lu R Rujun Tang R Ren‐Gen Xiong (Ordered Matter Science Research Center Nanchang University Nanchang P. R. China) G Guifu Zou (School of Energy, School of Optoelectronic Science and Engineering, School of Physical Science and Technology)

Abstract

Abstract Human hearing cannot sensitively detect sounds below 100 Hz, which can affect the physical well‐being and lead to dizziness, headaches, and nausea. Piezoelectric acoustic sensors still lack sensitivity to low‐frequency sounds owing to the low piezoelectric coefficient or high elastic modulus of materials. The low elastic modulus and substantial piezoelectric coefficient of molecular ferroelectric materials make them excellent candidates for acoustic sensors. In this study, the molecular ferroelectric, [(CH 3 ) 3 NCH 2 Cl]CdCl 3 , is used as a piezoelectric active layer in the construction of a piezoelectric acoustic sensor for low‐frequency sound detection. The sensor exhibits high sensitivity (47.43 mV Pa −1 cm −2 ) at 87 Hz, with an excellent level of frequency resolution (up to 0.1 Hz). This facilitates the accurate discrimination and detection of low‐frequency sounds, which is suitable for noise detection applications. The sensor differentiates between various musical instruments and heartbeats, and recognizes audio signals. This study highlights the potential of molecular ferroelectric materials in piezoelectric acoustic device applications, including noise detection, health monitoring, and human‐computer interactions.

Article Details

Volume / Issue Vol. 37, Issue 8
Published February 01, 2025
ISSN 0935-9648
Publisher Unknown Publisher

Journal Info

Advanced Materials

Unknown Publisher

ISSN: 0935-9648 Physical Sciences

Authors (18)

R

Ruonan Wang

State Key Laboratory of Common Mechanism Research for Major Diseases, Department of Biophysics and Structural Biology

L

Lutao Li

School of Energy, School of Optoelectronic Science and Engineering, School of Physical Science and Technology

J

Jiating Li

School of Energy School of Optoelectronic Science and Engineering School of Biology and Basic Medical Sciences School of Physical Science and Technology Soochow University Suzhou 215000 P. R. China

C

Chen Wang

S

Shan Cong

School of Energy, School of Optoelectronic Science and Engineering, State Key Laboratory of Bioinspired Interfacial Materials Science, Institute of Functional Nano and Soft Materials Laboratory

G

Guoxiang Zhao

State Key Laboratory of Structural Chemistry

X

Xinyu Du

C

Chao‐Ran Huang

School of Energy School of Optoelectronic Science and Engineering School of Biology and Basic Medical Sciences School of Physical Science and Technology Soochow University Suzhou 215000 P. R. China

H

Hengyu Cao

School of Energy, School of Optoelectronic Science and Engineering, School of Physical Science and Technology

W

Weiyu Cheng

School of Energy, School of Optoelectronic Science and Engineering, State Key Laboratory of Bioinspired Interfacial Materials Science, Institute of Functional Nano and Soft Materials Laboratory

Y

Yaqi Ye

C

Chengyuan Liu

National Synchrotron Radiation Laboratory

B

Bin Li

W

Wei‐Qiang Liao

Ordered Matter Science Research Center Nanchang University Nanchang P. R. China

Z

Zheng Lu

R

Rujun Tang

R

Ren‐Gen Xiong

Ordered Matter Science Research Center Nanchang University Nanchang P. R. China

G

Guifu Zou

School of Energy, School of Optoelectronic Science and Engineering, School of Physical Science and Technology