Molecular Chain Interpenetration–Enabled High Interfacial Compatibility of Ionic and Electronic Conductors for Stretchable Ionic Devices

Y Yaoxian Zheng (Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China) H Haichuan Ning (Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China) B Bicheng Zhao (Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China) Y Yuxuan Jiang (National Key Laboratory of Strength and Structural Integrity, Institute of Solid Mechanics, School of Aeronautic Science and Engineering, Beihang University) J Jitian Chen (Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China) Y Yuexiang Wu (Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China) D Du Nie (Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China) X Xinling Hu (Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China) Z Zijian Yan (Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China) R Ruijie Xie C Chenyang Shi N Naibo Lin (Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China)

Abstract

Abstract Ionic devices find applications such as flexible electronics and biomedicines and function by exploiting hybrid circuits of mobile ions and electrons. However, the poor interfacial compatibility of hard electronic conductors with soft ionic conductors in ionic devices leads to low deformability, sensitivity, electromechanical responses, and stability. Herein, an interpenetrating interface between silicone‐modified polyurethane/carbon nanotube electronic conductors and ionoelastomers in an ionic device using in situ polymerization is fabricated. A robust interpenetrating electronic/ionic conductor interface is realized through molecular chain entanglement and molecular forces (such as ion‐dipole interactions and H‐bonds), effectively enhancing the bonding strength and contact area between the components and resulting in an excellent flexibility, stability, and device performance. The electroadhesive prepared based on this strategy exhibits a superrobust shear strength of 317 kPa under a reduced voltage input of −4 V, and the diode and the transistor can undergo arbitrary deformation while maintaining the semiconductor device characteristics, including rectification and switching. In addition, electromechanical transducers exhibit sensitive electrical responses to various deformation signals. This solution to the interfacial compatibility problems of electronic and ionic conductors holds promise for the development of multifunctional ionic devices.

Article Details

Volume / Issue Vol. 37, Issue 16
Published April 01, 2025
ISSN 0935-9648
Publisher Unknown Publisher

Journal Info

Advanced Materials

Unknown Publisher

ISSN: 0935-9648 Physical Sciences

Authors (12)

Y

Yaoxian Zheng

Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China

H

Haichuan Ning

Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China

B

Bicheng Zhao

Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China

Y

Yuxuan Jiang

National Key Laboratory of Strength and Structural Integrity, Institute of Solid Mechanics, School of Aeronautic Science and Engineering, Beihang University

J

Jitian Chen

Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China

Y

Yuexiang Wu

Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China

D

Du Nie

Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China

X

Xinling Hu

Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China

Z

Zijian Yan

Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China

R

Ruijie Xie

C

Chenyang Shi

N

Naibo Lin

Research Institution for Biomimetics and Soft Matter The Higher Educational Key Laboratory for Biomedical Engineering of Fujian Province Research Center of Biomedical Engineering of Xiamen Fujian Key Laboratory of Advanced Materials Department of Biomaterials College of Materials Institute of Flexible Electronics (IFE, Future Technologies) Shenzhen Research Institute of Xiamen University Xiamen University Xiamen 361005 China