Modeling thermal effects in Heisenberg dimers initiated by fast magnetic field switching off

A Andrew Palii (Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of RAS 1 , Chernogolovka, Moscow Region 142432,) V Valeria Belonovich (Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of RAS 1 , Chernogolovka, Moscow Region 142432,) S Sergei Aldoshin (Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of RAS 1 , Chernogolovka, Moscow Region 142432,) B Boris Tsukerblat (Department of Chemistry, Ben-Gurion University of the Negev 3 , 84105 Beer-Sheva,)

Abstract

In this article, we analyze the thermal processes induced in the Heisenberg-type exchange coupled binuclear clusters by suddenly switching off the magnetic field initially applied to the system. The key result of the present study is the established correlation between the sign of the exchange parameter and the sign of the thermal effect. We have demonstrated that in the case of a ferromagnetic exchange, heat absorption (cooling) occurs, while if the exchange is antiferromagnetic, heat release (heating) takes place. This conclusion suggests a possibility to regard Heisenberg type dimers exhibiting ferromagnetic exchange as a class of low-temperature magnetic refrigerants that could be promising for practical applications.

Article Details

Volume / Issue Vol. 163, Issue 2
Published July 14, 2025
ISSN 0021-9606
Publisher American Institute of Physics

Journal Info

The Journal of Chemical Physics

American Institute of Physics

ISSN: 0021-9606 Physical Sciences

Authors (4)

A

Andrew Palii

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of RAS 1 , Chernogolovka, Moscow Region 142432,

V

Valeria Belonovich

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of RAS 1 , Chernogolovka, Moscow Region 142432,

S

Sergei Aldoshin

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of RAS 1 , Chernogolovka, Moscow Region 142432,

B

Boris Tsukerblat

Department of Chemistry, Ben-Gurion University of the Negev 3 , 84105 Beer-Sheva,