Mixed quantum–classical dynamics yields anharmonic Rabi oscillations
Abstract
We apply a mixed quantum–classical (MQC) approach to the quantum Rabi model, involving a classical optical field coupled self-consistently to a quantum two-level system. Under the rotating wave approximation, we analytically show that this approach yields persistent yet anharmonic Rabi oscillations, governed by an undamped and unforced Duffing equation. We consider the single-quantum limit, where we find that such anharmonic Rabi oscillations closely follow full-quantum results once zero-point energy is approximately enforced when initializing the optical field coordinate. Our findings provide guidance in the application of MQC dynamics to classes of problems involving small quantum numbers and far away from decoherence.
Article Details
Journal Info
The Journal of Chemical Physics
American Institute of Physics
Authors (2)
Ming-Hsiu Hsieh
Department of Chemistry, Northwestern University , 2145 Sheridan Road, Evanston, Illinois 60208,
Roel Tempelaar
Department of Chemistry, Institute for Quantum Information Research and Engineering, and Center for Molecular Quantum Transduction