Mixed quantum–classical dynamics yields anharmonic Rabi oscillations

M Ming-Hsiu Hsieh (Department of Chemistry, Northwestern University , 2145 Sheridan Road, Evanston, Illinois 60208,) R Roel Tempelaar (Department of Chemistry, Institute for Quantum Information Research and Engineering, and Center for Molecular Quantum Transduction)

Abstract

We apply a mixed quantum–classical (MQC) approach to the quantum Rabi model, involving a classical optical field coupled self-consistently to a quantum two-level system. Under the rotating wave approximation, we analytically show that this approach yields persistent yet anharmonic Rabi oscillations, governed by an undamped and unforced Duffing equation. We consider the single-quantum limit, where we find that such anharmonic Rabi oscillations closely follow full-quantum results once zero-point energy is approximately enforced when initializing the optical field coordinate. Our findings provide guidance in the application of MQC dynamics to classes of problems involving small quantum numbers and far away from decoherence.

Article Details

Volume / Issue Vol. 162, Issue 22
Published June 14, 2025
ISSN 0021-9606
Publisher American Institute of Physics

Journal Info

The Journal of Chemical Physics

American Institute of Physics

ISSN: 0021-9606 Physical Sciences

Authors (2)

M

Ming-Hsiu Hsieh

Department of Chemistry, Northwestern University , 2145 Sheridan Road, Evanston, Illinois 60208,

R

Roel Tempelaar

Department of Chemistry, Institute for Quantum Information Research and Engineering, and Center for Molecular Quantum Transduction