Marker‐Agnostic Tumor Anchoring Chimeras Enable pH‐Gated Immune Engagement

H Heleen Lauwers (Department of Pharmaceutics) J Jamie De Baere (Department of Pharmaceutics Ghent University Ghent Belgium) I Ilke Aernout (Ghent Research Group on Nanomedicines Ghent University Ghent Belgium) F Federica Cappellesso (Lab of Cellular and Molecular Immunology Brussel Center for Immunology Vrije Universiteit Brussel Brussels Belgium) S Stijn De Munter (Department of Diagnostic Sciences, Ghent University, Ghent, Belgium Cancer Research Institute Ghent (CRIG) Ghent Belgium) D Demi Defreyne (Department of Pharmaceutics, Ghent University, Belgium Cancer Research Institute Ghent (CRIG) Ghent Belgium) A Alexandra Neeser (The Raymond G. Perelman Center For Cellular and Molecular Therapeutics, Children's Hospital of Philadelphia, Philadelphia, PA, USA; Department of Pathology and Laboratory Medicine, Perelman School of Medicine, University of Pennsylvania, Philadelphia, PA, USA; Center for Cellular Immunotherapies, University of Pennsylvania, Philadelphia, PA, USA; Abramson Cancer Center University of Pennsylvania Philadelphia Pennsylvania USA) T Tomasz M. Grzywa (The Raymond G. Perelman Center For Cellular and Molecular Therapeutics, Children's Hospital of Philadelphia, Philadelphia, PA, USA; Department of Pathology and Laboratory Medicine, Perelman School of Medicine, University of Pennsylvania, Philadelphia, PA, USA; Center for Cellular Immunotherapies, University of Pennsylvania, Philadelphia, PA, USA; Abramson Cancer Center University of Pennsylvania Philadelphia Pennsylvania USA) V Victor Bosteels B Bart Vandekerckhove (Department of Diagnostic Sciences, Ghent University, Ghent, Belgium Cancer Research Institute Ghent (CRIG) Ghent Belgium) I Ine Lentacker (Department of Pharmaceutics, Ghent University, Belgium Cancer Research Institute Ghent (CRIG) Ghent Belgium) L Leyuan Ma (The Raymond G. Perelman Center For Cellular and Molecular Therapeutics, Children's Hospital of Philadelphia, Philadelphia, PA, USA; Department of Pathology and Laboratory Medicine, Perelman School of Medicine, University of Pennsylvania, Philadelphia, PA, USA; Center for Cellular Immunotherapies, University of Pennsylvania, Philadelphia, PA, USA; Abramson Cancer Center University of Pennsylvania Philadelphia Pennsylvania USA) J Jurgen Haustraete (VIB Protein Core, VIB‐UGent Center for Inflammation, Ghent, Belgium; Department for Medical Molecular Biology Ghent University Ghent Belgium) S Savvas N. Savvides B Bart N. Lambrecht D Damya Laoui B Benoit Louage (Department of Pharmaceutics) B Bruno G. De Geest (Department of Pharmaceutics)

Abstract

ABSTRACT Targeted cancer immunotherapies typically depend on cell surface antigens to direct immune responses. However, many tumors either lack tumor‐specific markers or downregulate their expression, limiting the applicability of antigen‐directed strategies. In contrast, tumor acidosis represents a nearly universal hallmark of solid cancers, arising from dysregulated metabolism that acidifies the extracellular tumor microenvironment (TME). Here, we leverage this feature to develop Marker‐Agnostic Tumor Anchoring Chimeras (MATRACs), pH‐sensitive fusion proteins that mediate ternary complex formation between cancer cells and immune effector cells in an antigen‐independent manner. MATRACs harness the diphtheria toxin translocation domain (tdDT), whose pH‐dependent conformational switch drives membrane insertion, allowing tdDT and its Fc‐fused form (tdDT‐Fc) to anchor selectively to cells in TME‐like acidity while remaining inactive at physiological pH. To demonstrate pH‐dependent immune activation, we designed a fluorescein‐tagged tdDT‐Fc variant that anchors to tumor cells in acidic conditions and presents a synthetic epitope enabling recruitment of antifluorescein CAR T cells. These findings establish tdDT‐based MATRACs as a modular, TME‐responsive platform for antigen‐agnostic immune engagement and support their potential for next‐generation pH‐targeted immunotherapies.

Article Details

Volume / Issue Vol. 65, Issue 28
Published July 06, 2026
ISSN 1433-7851
Publisher Wiley

Journal Info

Angewandte Chemie International Edition

Wiley

ISSN: 1433-7851 Physical Sciences

Authors (18)

H

Heleen Lauwers

Department of Pharmaceutics

J

Jamie De Baere

Department of Pharmaceutics Ghent University Ghent Belgium

I

Ilke Aernout

Ghent Research Group on Nanomedicines Ghent University Ghent Belgium

F

Federica Cappellesso

Lab of Cellular and Molecular Immunology Brussel Center for Immunology Vrije Universiteit Brussel Brussels Belgium

S

Stijn De Munter

Department of Diagnostic Sciences, Ghent University, Ghent, Belgium Cancer Research Institute Ghent (CRIG) Ghent Belgium

D

Demi Defreyne

Department of Pharmaceutics, Ghent University, Belgium Cancer Research Institute Ghent (CRIG) Ghent Belgium

A

Alexandra Neeser

The Raymond G. Perelman Center For Cellular and Molecular Therapeutics, Children's Hospital of Philadelphia, Philadelphia, PA, USA; Department of Pathology and Laboratory Medicine, Perelman School of Medicine, University of Pennsylvania, Philadelphia, PA, USA; Center for Cellular Immunotherapies, University of Pennsylvania, Philadelphia, PA, USA; Abramson Cancer Center University of Pennsylvania Philadelphia Pennsylvania USA

T

Tomasz M. Grzywa

The Raymond G. Perelman Center For Cellular and Molecular Therapeutics, Children's Hospital of Philadelphia, Philadelphia, PA, USA; Department of Pathology and Laboratory Medicine, Perelman School of Medicine, University of Pennsylvania, Philadelphia, PA, USA; Center for Cellular Immunotherapies, University of Pennsylvania, Philadelphia, PA, USA; Abramson Cancer Center University of Pennsylvania Philadelphia Pennsylvania USA

V

Victor Bosteels

B

Bart Vandekerckhove

Department of Diagnostic Sciences, Ghent University, Ghent, Belgium Cancer Research Institute Ghent (CRIG) Ghent Belgium

I

Ine Lentacker

Department of Pharmaceutics, Ghent University, Belgium Cancer Research Institute Ghent (CRIG) Ghent Belgium

L

Leyuan Ma

The Raymond G. Perelman Center For Cellular and Molecular Therapeutics, Children's Hospital of Philadelphia, Philadelphia, PA, USA; Department of Pathology and Laboratory Medicine, Perelman School of Medicine, University of Pennsylvania, Philadelphia, PA, USA; Center for Cellular Immunotherapies, University of Pennsylvania, Philadelphia, PA, USA; Abramson Cancer Center University of Pennsylvania Philadelphia Pennsylvania USA

J

Jurgen Haustraete

VIB Protein Core, VIB‐UGent Center for Inflammation, Ghent, Belgium; Department for Medical Molecular Biology Ghent University Ghent Belgium

S

Savvas N. Savvides

B

Bart N. Lambrecht

D

Damya Laoui

B

Benoit Louage

Department of Pharmaceutics

B

Bruno G. De Geest

Department of Pharmaceutics