Magic wavelengths with QED correction for the 23 <i>S</i> 1 → 23 <i>P</i> <i>J</i> transitions of helium-4
Abstract
A series of magic wavelengths for the 23S1 → 23PJ (J = 0, 1, 2) transitions in helium is determined with high precision using the relativistic configuration interaction combined with the radiative potential method. The calculation explicitly incorporates relativistic, finite nuclear mass, and quantum electrodynamic corrections through the inclusion of mass shift and radiative potential operators into the Dirac–Coulomb–Breit Hamiltonian. The resulting magic wavelengths lie entirely within the visible spectrum (400–700 nm) and converge to seven significant digits, making them directly accessible for experimental verification. These accurate predictions serve as benchmarks for testing atomic structure theory and support the development of state-insensitive optical trapping schemes in precision spectroscopy.
Article Details
Journal Info
The Journal of Chemical Physics
American Institute of Physics
Authors (6)
Shan-Shan Lu
College of Physics and Telecommunication Engineering, Zhoukou Normal University 1 , Zhoukou 466001,
Ji-Tao Li
College of Physics and Telecommunication Engineering, Zhoukou Normal University 1 , Zhoukou 466001,
Yu-Jie Wang
School of Life Sciences, Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, and Hubei Key Laboratory of Genetic Regulation and Integrative Biology, Central China Normal University
Wen-Juan Mao
College of Physics and Telecommunication Engineering, Zhoukou Normal University 1 , Zhoukou 466001,
Zhou-Run Zhu
College of Physics and Telecommunication Engineering, Zhoukou Normal University 1 , Zhoukou 466001,
Fang-Fei Wu
College of Sciences, China Jiliang University 2 , Hangzhou 310018,