Magic wavelengths with QED correction for the 23 <i>S</i> 1 → 23 <i>P</i> <i>J</i> transitions of helium-4

S Shan-Shan Lu (College of Physics and Telecommunication Engineering, Zhoukou Normal University 1 , Zhoukou 466001,) J Ji-Tao Li (College of Physics and Telecommunication Engineering, Zhoukou Normal University 1 , Zhoukou 466001,) Y Yu-Jie Wang (School of Life Sciences, Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, and Hubei Key Laboratory of Genetic Regulation and Integrative Biology, Central China Normal University) W Wen-Juan Mao (College of Physics and Telecommunication Engineering, Zhoukou Normal University 1 , Zhoukou 466001,) Z Zhou-Run Zhu (College of Physics and Telecommunication Engineering, Zhoukou Normal University 1 , Zhoukou 466001,) F Fang-Fei Wu (College of Sciences, China Jiliang University 2 , Hangzhou 310018,)

Abstract

A series of magic wavelengths for the 23S1 → 23PJ (J = 0, 1, 2) transitions in helium is determined with high precision using the relativistic configuration interaction combined with the radiative potential method. The calculation explicitly incorporates relativistic, finite nuclear mass, and quantum electrodynamic corrections through the inclusion of mass shift and radiative potential operators into the Dirac–Coulomb–Breit Hamiltonian. The resulting magic wavelengths lie entirely within the visible spectrum (400–700 nm) and converge to seven significant digits, making them directly accessible for experimental verification. These accurate predictions serve as benchmarks for testing atomic structure theory and support the development of state-insensitive optical trapping schemes in precision spectroscopy.

Article Details

Volume / Issue Vol. 164, Issue 11
Published March 21, 2026
ISSN 0021-9606
Publisher American Institute of Physics

Journal Info

The Journal of Chemical Physics

American Institute of Physics

ISSN: 0021-9606 Physical Sciences

Authors (6)

S

Shan-Shan Lu

College of Physics and Telecommunication Engineering, Zhoukou Normal University 1 , Zhoukou 466001,

J

Ji-Tao Li

College of Physics and Telecommunication Engineering, Zhoukou Normal University 1 , Zhoukou 466001,

Y

Yu-Jie Wang

School of Life Sciences, Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, and Hubei Key Laboratory of Genetic Regulation and Integrative Biology, Central China Normal University

W

Wen-Juan Mao

College of Physics and Telecommunication Engineering, Zhoukou Normal University 1 , Zhoukou 466001,

Z

Zhou-Run Zhu

College of Physics and Telecommunication Engineering, Zhoukou Normal University 1 , Zhoukou 466001,

F

Fang-Fei Wu

College of Sciences, China Jiliang University 2 , Hangzhou 310018,