Linking photoelectron circular dichroism to the asymmetric total photoemission yield measured in aerosol nanoparticles of tyrosine

Abstract

Abstract Spectroscopic techniques that are sensitive to molecular chirality are important analytical tools to quantitatively determine enantiomeric excess and purity of chiral molecular samples. Many chiroptical processes however produce weak enantio-specific asymmetries due to their origin relying on weak magnetic dipole or electric quadrupole effects. Photoelectron circular dichroism (PECD) in contrast, is an intense effect, that is fully contained in the electric dipole description of light matter interaction and creates a chiral asymmetry in the photoelectron angular distribution. Here, we demonstrate that this chiral signature in the angular distribution of emitted electrons can be translated into the total photoemission yield for particulate matter. The resulting chiral asymmetry of the photoemission yield (CAPY), mediated by the attenuation of light within condensed particles, can be detected experimentally without requiring high vacuum systems and electron spectrometers. This effect can be exploited as an analytical tool with high sensitivity to chirality and enantiopurity for studies of chiral organic and hybrid submicron particles in environmental, biomedical or catalytic applications.