Ionic Hydrogen‐Bonded Organic Frameworks: A New Type of Porous Organic Solid Base
Abstract
Abstract Solid base offers advantages in terms of the ease of handling, environmentally sustainable processes, and tunable interfacial properties. Despite of these benefits, the exploration of new solid bases remains challenging and is an underdeveloped area of research. In this work, we report the discovery of the inherent basicity of hydrogen‐bonded organic frameworks (HOFs). The high crystallinity of HOFs enables us to monitor the precise structure changes and proton transfer process during acid‐base neutralization reaction through single‐crystal X‐ray diffraction. With this information, the origin of basicity and the underlying mechanism can be identified, which further guide us to discover other porous solid bases and unveil the universal characteristic of some anionic HOFs. The practical use of the porous solid bases was demonstrated by base‐catalyzed reactions, exhibiting high activity and selectivity. This study enriches the solid‐base family by introducing a type of materials featured with high porosity, high crystallinity, and modular structure.
Article Details
Authors (10)
Ying Hou
Han‐Ru Fang
State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou People's Republic of China
Yu‐Lin Li
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou P.R. China
An‐An Zhang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou P.R. China
Xin‐Song Huang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou P.R. China
Lei Cai
New Cornerstone Science Laboratory, Beijing Advanced Innovation Center for Integrated Circuits, School of Integrated Circuits, Peking University, Beijing, China.
Qi Yin
School of Materials Science and Engineering
Rui Wang
Jin‐Lin Li
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou P.R. China
Tian‐Fu Liu
State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou People's Republic of China