Interfacial and density fluctuations in a lattice model of motility-induced phase separation

L Liheng Yao R Robert L. Jack (Yusuf Hamied Department of Chemistry, University of Cambridge)

Abstract

We analyze motility-induced phase separation and bubbly phase separation in a two-dimensional lattice model of self-propelled particles. We compare systems where the dense (liquid) phase has slab and droplet geometries. We find that interfacial fluctuations of the slab are well-described by capillary wave theory, despite the existence of bubbles in the dense phase. We attribute this to a separation of time scales between bubble expulsion and interfacial relaxation. We also characterize the dependence of liquid and vapor densities on the curvature of the liquid droplet, as well as the density fluctuations inside the phases. The vapor phase behaves similarly to an equilibrium system, displaying a Laplace pressure effect that shifts its density, and Gaussian density fluctuations. The liquid phase has large non-Gaussian fluctuations, but this is not accompanied by a large density shift, contrary to the equilibrium case. Nevertheless, the shift of the vapor density can be used to infer an effective surface tension that appears to also quantify capillary wave fluctuations.

Article Details

Volume / Issue Vol. 162, Issue 11
Published March 21, 2025
ISSN 0021-9606
Publisher American Institute of Physics

Journal Info

The Journal of Chemical Physics

American Institute of Physics

ISSN: 0021-9606 Physical Sciences

Authors (2)

L

Liheng Yao

R

Robert L. Jack

Yusuf Hamied Department of Chemistry, University of Cambridge