Hopping conduction in GeSiSn alloys: Impact of structural disorder on electrical transport

S Serhiy Kondratenko (Taras Shevchenko National University of Kyiv 1 Faculty of Physics, , 64 Volodymyrs’ka St., 01601 Kyiv,) O Oleksandr Datsenko (Taras Shevchenko National University of Kyiv 1 Faculty of Physics, , 64 Volodymyrs’ka St., 01601 Kyiv,) H Hryhorii Stanchu (Institute for Nanoscience and Engineering, University of Arkansas 4 , Fayetteville, Arkansas 72701,) A Andrii Pocherpailo (Taras Shevchenko National University of Kyiv 1 Faculty of Physics, , 64 Volodymyrs’ka St., 01601 Kyiv,) P Petro M. Lytvyn (V. E. Lashkaryov Institute of Semiconductors Physics 3 , NAS of Ukraine, 41 pr. Nauki, 03028 Kyiv,) M Morgan E. Ware (Institute of Nano Science and Engineering, University of Arkansas 2 , Fayetteville, Arkansas 72701,) S Serhii Maliuta (National Technical University of Ukraine “Igor Sikorsky KPI,” 5 Microelectronics Department, 37 Beresteyskyi av., 03056 Kyiv,) S Shui-Qing (Fisher) Yu (Department of Electrical Engineering, University of Arkansas 4 , Fayetteville, Arkansas 72701,) Y Yuriy I. Mazur (Institute for Nanoscience and Engineering, University of Arkansas 1 , Fayetteville, Arkansas 72701,) G Gregory J. Salamo (Institute for Nanoscience and Engineering, University of Arkansas 1 , Fayetteville, Arkansas 72701,)

Abstract

Temperature-dependent charge transport in epitaxial GeSiSn films with varying thicknesses and Si and Sn content, grown on Ge/Si(001) substrates, was investigated using admittance spectroscopy. The conductance exhibits a crossover from Mott variable-range hopping at low temperatures to thermally activated conduction at higher temperatures. Below 150 K, carriers move via localized states in the band tails, with hopping parameters governed by the density and spatial distribution of disorder-induced states. Increasing nominal Sn concentration and thickness enhances structural disorder and Sn segregation, leading to a higher density of states and reduced hopping length. Scanning capacitance microscopy reveals variations in charge-carrier concentration in high-Sn films, indicating the presence of coexisting p-type and n-type regions at the microscale, consistent with compositional fluctuations, Sn segregation, and microstrain. These results demonstrate that transport in GeSiSn alloys is primarily dominated by disorder-assisted hopping at low temperatures, establishing a quantitative link between microscopic disorder and macroscopic electrical response in metastable group-IV semiconductors.

Article Details

Volume / Issue Vol. 139, Issue 20
Published May 28, 2026
ISSN 0021-8979
Publisher American Institute of Physics

Journal Info

Journal of Applied Physics

American Institute of Physics

ISSN: 0021-8979 Physical Sciences

Authors (10)

S

Serhiy Kondratenko

Taras Shevchenko National University of Kyiv 1 Faculty of Physics, , 64 Volodymyrs’ka St., 01601 Kyiv,

O

Oleksandr Datsenko

Taras Shevchenko National University of Kyiv 1 Faculty of Physics, , 64 Volodymyrs’ka St., 01601 Kyiv,

H

Hryhorii Stanchu

Institute for Nanoscience and Engineering, University of Arkansas 4 , Fayetteville, Arkansas 72701,

A

Andrii Pocherpailo

Taras Shevchenko National University of Kyiv 1 Faculty of Physics, , 64 Volodymyrs’ka St., 01601 Kyiv,

P

Petro M. Lytvyn

V. E. Lashkaryov Institute of Semiconductors Physics 3 , NAS of Ukraine, 41 pr. Nauki, 03028 Kyiv,

M

Morgan E. Ware

Institute of Nano Science and Engineering, University of Arkansas 2 , Fayetteville, Arkansas 72701,

S

Serhii Maliuta

National Technical University of Ukraine “Igor Sikorsky KPI,” 5 Microelectronics Department, 37 Beresteyskyi av., 03056 Kyiv,

S

Shui-Qing (Fisher) Yu

Department of Electrical Engineering, University of Arkansas 4 , Fayetteville, Arkansas 72701,

Y

Yuriy I. Mazur

Institute for Nanoscience and Engineering, University of Arkansas 1 , Fayetteville, Arkansas 72701,

G

Gregory J. Salamo

Institute for Nanoscience and Engineering, University of Arkansas 1 , Fayetteville, Arkansas 72701,