Higher order Magnus expansion for driven two-level quantum dynamics

C Chen Wei (Department of Mechanical and Aerospace Engineering, University of California Los Angeles) F Frank Großmann (Institut für Theoretische Physik, Technische Universität Dresden , 01062 Dresden,)

Abstract

We investigate the Magnus expansion for a generic time-dependent two-level system under single-axis driving. By virtue of the su(2) Lie algebra, the expansion is decomposed into a commutator-free form. To illustrate the usefulness of the gained expression, we then revisit the Landau–Zener–Stückelberg–Majorana model, with a focus on non-adiabatic transitions as well as the Stokes phase. In addition, the semiclassical Rabi model is systematically treated by determining the Floquet quasienergy up to different orders. We demonstrate how to employ suitable picture transformations as well as how to enforce the symmetry of the underlying model to guarantee convergence of the expansion as well as to achieve satisfactory agreement with the exact results. For both models that we studied, it turns out that a third order approximation yields results that are in next to perfect agreement with exact analytical ones. Surprisingly, in the case of the semiclassical Rabi model, even the second order Magnus approximation in the adiabatic picture produces almost exact results for a large parameter range.

Article Details

Volume / Issue Vol. 164, Issue 22
Published June 14, 2026
ISSN 0021-9606
Publisher American Institute of Physics

Journal Info

The Journal of Chemical Physics

American Institute of Physics

ISSN: 0021-9606 Physical Sciences

Authors (2)

C

Chen Wei

Department of Mechanical and Aerospace Engineering, University of California Los Angeles

F

Frank Großmann

Institut für Theoretische Physik, Technische Universität Dresden , 01062 Dresden,