Geminal Atom Catalysts with Minimized d-Orbital Holes Enable β-Elimination-Resistant C(sp <sup>2</sup> )–C(sp <sup>3</sup> ) Cross-Coupling

Q Qiang Wang T Tan Li P Pengru Huang (Institute for Functional Intelligent Materials) Q Qi Yu (Department of Chemistry, Advanced Institute of Future Energy, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Porous Materials for Separation and Conversion) K Kun Fu (School of Materials Science and Engineering) S Shibo Xi X Xiaocang Han (School of Materials Science and Engineering) J Jingcong Hu X Xiaoxu Zhao H Haipei Shao (Department of Chemistry, Faculty of Science, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore) M Ming Lin (Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Innovis #08-03, Singapore 138634, Singapore) Y Yang Meng (Department of Chemistry) J Jinxing Chen (Department of Chemistry) J Jiali Li (Department of Chemistry) C Caozheng Diao (Singapore Synchrotron Light Source (SSLS)) X Xiao Hai (Department of Chemistry) Y Yulin Wang (Department of Chemistry) X Xingjie Fu (Department of Chemistry) J Jialu Sun (Department of Chemistry) K Kostya S. Novoselov R Richard Y. Liu J Jun Li J Jiong Lu

Article Details

Volume / Issue Vol. 148, Issue 15
Published April 22, 2026
Pages 16138-16150
ISSN 0002-7863
Publisher American Chemical Society

Journal Info

Journal of the American Chemical Society

American Chemical Society

ISSN: 0002-7863 Physical Sciences

Authors (23)

Q

Qiang Wang

T

Tan Li

P

Pengru Huang

Institute for Functional Intelligent Materials

Q

Qi Yu

Department of Chemistry, Advanced Institute of Future Energy, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Porous Materials for Separation and Conversion

K

Kun Fu

School of Materials Science and Engineering

S

Shibo Xi

X

Xiaocang Han

School of Materials Science and Engineering

J

Jingcong Hu

X

Xiaoxu Zhao

H

Haipei Shao

Department of Chemistry, Faculty of Science, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore

M

Ming Lin

Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Innovis #08-03, Singapore 138634, Singapore

Y

Yang Meng

Department of Chemistry

J

Jinxing Chen

Department of Chemistry

J

Jiali Li

Department of Chemistry

C

Caozheng Diao

Singapore Synchrotron Light Source (SSLS)

X

Xiao Hai

Department of Chemistry

Y

Yulin Wang

Department of Chemistry

X

Xingjie Fu

Department of Chemistry

J

Jialu Sun

Department of Chemistry

K

Kostya S. Novoselov

R

Richard Y. Liu

J

Jun Li

J

Jiong Lu