Exploring the chemical composition and processes of submicron aerosols in Delhi using aerosol chemical speciation monitor driven factor analysis

Abstract

Abstract Wintertime non-refractory submicron particulate matter (NR-PM 1 ) species were measured in Delhi with an Aerodyne Aerosol Chemical Speciation Monitor (ACSM) during February–March 2018. The average NR-PM 1 mass concentration throughout the study was 58.0 ± 42.6 µg m −3 , where the contribution of organic aerosol (OA) was 69% of the total NR-PM 1 . In Delhi, chloride (10%) was the main inorganic contributor, followed by ammonium (8%), sulfate (7%), and nitrate (6%), contrasting with the prevalence of sulfate in most urban environments. Source apportionment analysis of the OA identified five major factors, including three primary contributors: hydrocarbon-like OA (HOA), biomass burning OA (BBOA), cooking-related OA (COA) and two secondary contributors: oxygenated primary OA (OPOA), and more-oxidized oxygenated OA (MO-OOA). A 19% rise in OPOA concentration was observed during high chloride episodes, suggesting the potential role of chloride in the atmospheric chemical transformation of OA. Traffic emissions significantly contribute to ambient OA, accounting for at least 41% of the total OA mass. Furthermore, the OA exhibited low oxidation levels regardless of its source. The f 44 : f 43 analysis revealed slower atmospheric oxidization of OA compared to other urban locations worldwide. Further investigations, including chamber experiments tailored to the Delhi atmosphere, are necessary to elucidate the atmospheric oxidants and the genesis of secondary OA alongside primary emissions.