Exact factorization ansatz of the ground state many-body wave function: A case study of quartic potential problem

Z Zhiyuan Yin (University of California, San Diego , , , ,) Y Yi Deng (Department of Chemistry) X Xinyao Wang (Biomedical Pioneering Innovation Center) C Chen Li (Sibley School of Mechanical and Aerospace Engineering, Cornell University, Ithaca, NY, USA.)

Abstract

We propose an explicit factorized formula for the ground state many-body wave function of a model quartic potential problem in two and three dimensions, using our recently developed method for solving Schrödinger equations. Our novel formula has a clear real-space structure: it is exactly factorized into three parts, including a non-integer pre-exponential power factor, dominant decaying terms on the exponent, and a modulator function, which is of minor importance. This result is a generalization of our previously obtained exact formula for the 1-body wave function. As in the 1-body case, here we show that for many-body ground wave functions that cannot achieve variable separation, our method is still far more efficient than the conventional basis expansion method both in representing the wave function and in calculating the energy. The exact factorization ansatz proposed in the present case study shall provide important insight into the general structure of many-body wave functions.

Article Details

Volume / Issue Vol. 163, Issue 8
Published August 28, 2025
ISSN 0021-9606
Publisher American Institute of Physics

Journal Info

The Journal of Chemical Physics

American Institute of Physics

ISSN: 0021-9606 Physical Sciences

Authors (4)

Z

Zhiyuan Yin

University of California, San Diego , , , ,

Y

Yi Deng

Department of Chemistry

X

Xinyao Wang

Biomedical Pioneering Innovation Center

C

Chen Li

Sibley School of Mechanical and Aerospace Engineering, Cornell University, Ithaca, NY, USA.