Environmentally friendly polymers are used to enhance the water retention capacity of waste residue and the potential for vegetation growth

Abstract

The large pores and lack of water storage capacity limit the ecological rehabilitation of the waste residue. Modified hydrophilic polyurethane (W-OH) was used to improve the water retention of the residue. The water retention capacity of residues with different mass concentrations (1%, 3%, and 5%) of W-OH solution based on water mass was evaluated for several drying-wetting (D-W) cycles at 30°C and 50°C. The plant growth experiment investigated the plant growth status of waste residue before and after adding W-OH, to demonstrate the excellent water retention of W-OH under the same waste residue. Infiltration tests showed that W-OH effectively increased the volumetric water content (VWC) of waste residue and reduced its drying time. Untreated residue had 11.62% saturated initial VWC and 152 h drying time; 3% and 5% W-OH groups showed similar results (17.63%−18.09% VWC, 288–304 h drying time), so 3% W-OH is recommended for less usage. After 4 dry-wet cycles, both groups had reduced VWC and drying time. However, the 3% W-OH-treated residue still exhibited better water retention. A dense membrane is formed by W-OH solution around waste residue particles, enclosing/connecting particles, filling pores (reducing large ones), increasing capillary water storage, and hindering water evaporation. Degraded by more D-W cycles and higher temperature, the membrane weakens water retention, yet W-OH-treated residue still has better water retention than the untreated residue. Water retention of improved waste residue was enhanced, and plant growth promoted, per plant growth tests. After 21-day planting, Amorpha fruticosa in 3% W-OH-treated residue had better growth parameters than in untreated residue. This means that the waste grade treated with 3% W-OH can provide more water for plants to meet their growth needs.