Entropic Control of the Helicity Inversion Rates of Twisted Metallomacrocycles by Reversible and Regioselective Deprotonation

T Tomoki Nakajima (Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan) S Shohei Tashiro (Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan) M Masahiro Ehara (Research Center for Computational Science, Institute for Molecular Science, SOKENDAI, 38 Nishigo-Naka, Myodaiji, Okazaki 444-8585, Japan) M Mitsuhiko Shionoya (Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan)

Article Details

Volume / Issue Vol. 148, Issue 5
Published February 11, 2026
Pages 5338-5346
ISSN 0002-7863
Publisher American Chemical Society

Journal Info

Journal of the American Chemical Society

American Chemical Society

ISSN: 0002-7863 Physical Sciences

Authors (4)

T

Tomoki Nakajima

Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

S

Shohei Tashiro

Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

M

Masahiro Ehara

Research Center for Computational Science, Institute for Molecular Science, SOKENDAI, 38 Nishigo-Naka, Myodaiji, Okazaki 444-8585, Japan

M

Mitsuhiko Shionoya

Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan