Enantioselective Total Syntheses of (+)-Aconicarmichinium C and (+)-Pendulumine I: Strategic Use of a Bridgehead Enone via a Kinetic-Resolution-Enabled Intermolecular Diels–Alder Reaction

Wenhao Zhang

School of Physical Science and Technology, ShanghaiTech University, 393 Middle Huaxia Road, Shanghai 201210, China

Qilin Xue

State Key Laboratory of Chemical Biology, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China

Dawei Ma

State Key Laboratory of Chemical Biology, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China

Xiangbo Zhao

State Key Laboratory of Chemical Biology, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China