Distal Scaffold Flexibility Modulates Eyring Activation Parameters in Re(I) Substitution Reactions: A Case for Dynamics as the “Thematic Third Coordination Sphere”

A Alec T. Larson (Department of Chemistry, University of Texas at Austin, Austin, 105 E 24th St, Austin, Texas 78712, United States) S Serhii Vasylevskyi (Department of Chemistry) M Michael J. Rose (Department of Chemistry, University of Texas at Austin, Austin, 105 E 24th St, Austin, Texas 78712, United States)

Article Details

Volume / Issue Vol. 147, Issue 31
Published August 06, 2025
Pages 27341-27354
ISSN 0002-7863
Publisher American Chemical Society

Journal Info

Journal of the American Chemical Society

American Chemical Society

ISSN: 0002-7863 Physical Sciences

Authors (3)

A

Alec T. Larson

Department of Chemistry, University of Texas at Austin, Austin, 105 E 24th St, Austin, Texas 78712, United States

S

Serhii Vasylevskyi

Department of Chemistry

M

Michael J. Rose

Department of Chemistry, University of Texas at Austin, Austin, 105 E 24th St, Austin, Texas 78712, United States