Cooperative Activation of CO and Pyridine by an Aluminum(I) Complex Ligated with a Silylene–Borane Ligand
Abstract
Abstract Cooperative main‐group systems based on alumylenes are highly attractive due to their potential for activating and transforming inert chemical bonds and small molecules. However, their development has been hindered by the scarcity of suitable supporting ligands. Herein, we report the synthesis of an amphiphilic carboranyl silylene–borane ligand ( 1 ) and demonstrate its effectiveness in stabilizing an aluminum(I) complex 2 . Complex 2 has been unambiguously characterized by spectroscopic analysis, X‐ray diffraction analysis, and DFT calculations, which reveals a unique structure featuring both silicon(II)→aluminum(I) and aluminum(I)→boron(III) donor–acceptor bonds. The synergistic interplay between the silylene–borane ligand and the aluminum(I) center in 2 drives its unusual reactivity toward CO and pyridine activation, facilitating cleavage of the C≡O bond and dearomatization of pyridine.
Article Details
Authors (4)
Jinghuang Lv
State Key Laboratory and Institute of Elemento‐Organic Chemistry Frontiers Science Center for New Organic Matter Academy for Advanced Interdisciplinary Studies College of Chemistry Nankai University Tianjin 300071 China
Xiao Fang
Fanshu Cao
State Key Laboratory and Institute of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, College of Chemistry
Zhenbo Mo
State Key Laboratory of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, College of Chemistry