Clinically Accurate Diagnosis of Alzheimer's Disease via Single‐Molecule Bioelectronic Label‐Free Profiling of Multiple Blood Extracellular Vesicle Biomarkers

J Jintao Zheng X Xiaohong Jiang S Shiyao Bai (School of Medicine The Chinese University of Hong Kong (CUHK) Shenzhen 518172 China) M Minchao Lai (Department of Neurology First Affiliated Hospital of Shantou University Medical College Shantou China) J Jiacheng Yu (Molecular Medicine Program, The Hospital for Sick Children) M Mingxi Chen R Runzhi Zhou (Faculty of Biotechnology and Food Engineering Guangdong Technion‐Israel Institute of Technology (GTIIT) Shantou China) Y Yue Jia (Department of Biotechnology and Food Engineering Guangdong Technion‐Israel Institute of Technology (GTIIT) Shantou 515063 China) H Haoyang Yan (Faculty of Biotechnology and Food Engineering Guangdong Technion‐Israel Institute of Technology (GTIIT) Shantou China) Z Zheng Liang (Frontiers Science Center for Transformative Molecules, School of Chemistry and Chemical Engineering) D Dian Wang C Chuyan Wu (Shantou University Medical College (SUMC) Shantou 515041 China) S Shan Liu C Chenzhong Li (School of Medicine The Chinese University of Hong Kong (CUHK) Shenzhen 518172 China) J Jinguang Yang (Key Laboratory of Tobacco Pest Monitoring Controlling and Integrated Management Tobacco Research Institute of Chinese Academy of Agricultural Sciences Qingdao 266101 China) Y Yang Luo C Cheng Jiang (School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore) K Keying Guo (Key Lab for Special Functional Materials of Ministry of Education, National & Local Joint Engineering Research Center for High-efficiency Display and Lighting Technology, School of Nano Science and Materials Engineering, Collaborative Innovation Center of Nano Functional Materials and Applications)

Abstract

Abstract Alzheimer's disease (AD) is a progressive neurodegenerative disorder with no cure, making early diagnosis critical for mitigating its impact. Blood extracellular vesicles (EVs) hold promises as biomarkers for AD diagnosis, but current detection technologies lack the sensitivity and multiplexing capabilities needed for efficient diagnosis. Here, a novel label‐free bioelectronic platform is presented based on an organic electrochemical transistor (OECT) integrated with a microelectrode array (MEA) for ultrasensitive detection of AD biomarkers in blood EVs, including amyloid‐β (Aβ 1‐40 and Aβ 1‐42 ), total tau (t‐tau), and phosphorylated tau (p‐tau 181 ). This platform achieves a detection limit as low as the zeptomolar (zM) level, enabling the detection of single‐molecule targets. It provides a comprehensive multiplexed diagnostic model capable of delivering results within 20 min. Notably, the systematic integration of multiple AD biomarkers in blood EVs is demonstrated to significantly enhance diagnostic accuracy. This study presents a novel EVs‐based multiplexed diagnostic model for AD, correctly classifying all clinical samples ( n = 40), far exceeding the accuracy of a single biomarker. With its high sensitivity and rapid turnaround, this platform enables reliable AD diagnosis and holds the potential for tracking disease progression, offering a transformative tool to combat the societal burden of AD.

Article Details

Volume / Issue Vol. 37, Issue 37
Published September 01, 2025
ISSN 0935-9648
Publisher Unknown Publisher

Journal Info

Advanced Materials

Unknown Publisher

ISSN: 0935-9648 Physical Sciences

Authors (18)

J

Jintao Zheng

X

Xiaohong Jiang

S

Shiyao Bai

School of Medicine The Chinese University of Hong Kong (CUHK) Shenzhen 518172 China

M

Minchao Lai

Department of Neurology First Affiliated Hospital of Shantou University Medical College Shantou China

J

Jiacheng Yu

Molecular Medicine Program, The Hospital for Sick Children

M

Mingxi Chen

R

Runzhi Zhou

Faculty of Biotechnology and Food Engineering Guangdong Technion‐Israel Institute of Technology (GTIIT) Shantou China

Y

Yue Jia

Department of Biotechnology and Food Engineering Guangdong Technion‐Israel Institute of Technology (GTIIT) Shantou 515063 China

H

Haoyang Yan

Faculty of Biotechnology and Food Engineering Guangdong Technion‐Israel Institute of Technology (GTIIT) Shantou China

Z

Zheng Liang

Frontiers Science Center for Transformative Molecules, School of Chemistry and Chemical Engineering

D

Dian Wang

C

Chuyan Wu

Shantou University Medical College (SUMC) Shantou 515041 China

S

Shan Liu

C

Chenzhong Li

School of Medicine The Chinese University of Hong Kong (CUHK) Shenzhen 518172 China

J

Jinguang Yang

Key Laboratory of Tobacco Pest Monitoring Controlling and Integrated Management Tobacco Research Institute of Chinese Academy of Agricultural Sciences Qingdao 266101 China

Y

Yang Luo

C

Cheng Jiang

School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore

K

Keying Guo

Key Lab for Special Functional Materials of Ministry of Education, National & Local Joint Engineering Research Center for High-efficiency Display and Lighting Technology, School of Nano Science and Materials Engineering, Collaborative Innovation Center of Nano Functional Materials and Applications