Chaos in nonequilibrium two-temperature ( <i>T</i> <i>x</i> , <i>T</i> <i>y</i> ) Nosé–Hoover cell models
Abstract
We revisit a two-temperature Nosé–Hoover wanderer particle embedded in a two-dimensional periodic 2 × 2 cell with four smooth repulsive corners at (x, y) = (±1, ±1) to explore chaos with anisotropic thermostatting. The model employs separate thermostats in the x and y directions, enabling controlled deviations from equilibrium. By integrating the full six-dimensional equations of motion and computing the complete Lyapunov spectrum, we confirm chaos and quantify phase-space contraction from the fully resolved six-dimensional Lyapunov spectrum. The total contraction rate, interpreted as entropy production, increases nonlinearly with the thermostat anisotropy, deviating from the quadratic dependence expected from linear-response theory, Λ ∝ δ2. We analyze two functional forms for the entropy-production rate, Λ(δ) (with δ = 0.5 − Ty): (i) a quadratic-plus-quartic expansion, consistent with linear-response expectations, and (ii) a power law, Λ ∝ δ2.44. While the latter captures the low-driving regime slightly better, the former more accurately describes the strongly driven regime and remains consistent with linear-response theory near equilibrium. An empirical linear relation between dissipation and phase-space dimensionality loss is also identified, Λ ≈ (DKY − 6)/3, where DKY is the approximate Kaplan–Yorke dimension. Momentum statistics show a significant non-Gaussian behavior under strong driving. Despite its dissipative nature, the model remains strictly time-reversible, offering a pedagogically rich example of microscopic reversibility coexisting with macroscopic entropy production.
Article Details
Journal Info
The Journal of Chemical Physics
American Institute of Physics
Authors (4)
Hesam Arabzadeh
Department of Chemistry, University of Missouri 1 , Columbia, Missouri 65211-7600,
Carol Griswold Hoover
Ruby Valley Research Institute, Unit 109 2 , 2870 Ruby Vista Drive, Elko, Nevada 89801,
William Graham Hoover
Ruby Valley Research Institute, Unit 109 2 , 2870 Ruby Vista Drive, Elko, Nevada 89801,
Brad Lee Holian
Theoretical Division, Los Alamos National Laboratory 2 , Los Alamos, New Mexico 87545,