Carbon Doped Boron Nitride Nano‐Coatings for Durable, Low Emissivity Glass Windows

A Abhijit Biswas (Department of Materials Science and Nanoengineering Rice University Houston Texas USA) S Shancheng Wang (Department of Electronic Engineering The Chinese University of Hong Kong Shatin, N.T. Hong Kong SAR 999077 China) C Cody L. Milne (Department of Physics Arizona State University Tempe AZ 85287 USA) G Gustavo A. Alvarez M Md Akibul Islam (Department of Mechanical & Industrial Engineering University of Toronto 5 King's College Road Toronto M5S 3G8 Canada) T Tymofii S. Pieshkov (Department of Materials Science and Nanoengineering Rice University Houston Texas 77005 USA) T Tanguy Terlier (SIMS laboratory, Shared Equipment Authority, Rice University, 6100 Main Street, Houston, Texas 77005, United States) T Tao Li J Jishnu Murukeshan (Department of Materials Science and Nanoengineering Rice University Houston Texas USA) T Tia Gray (Department of Materials Science and Nanoengineering Rice University Houston Texas USA) J Jaejun Lee R Robert Vajtai (Department of Materials Science and Nanoengineering, Rice University 1 , Houston, Texas 77005,) Y Yuji Zhao (Department of Electrical and Computer Engineering, Rice University 1 , Houston, Texas 77005,) T Tobin Filleter Z Zhiting Tian (Sibley School of Mechanical and Aerospace Engineering, Cornell University, Ithaca, NY, USA.) A Arunima K. Singh (Department of Physics, Arizona State University , Tempe, Arizona 85287-1504,) Y Yi Long (School of Materials Science and Engineering) P Pulickel M. Ajayan

Abstract

AbstractEnergy‐efficient, durable low‐emissivity (low‐E) glass windows are in demand for reducing energy consumption and comfortable living environments. However, commercial low‐E coating materials are expensive, prone to abrasion, and hence coated only on the interior side of windows, limiting their energy efficiency. Here, a new material is introduced, namely chemically inert and transparent carbon (C) doped boron nitride (BN) nano‐coatings on glass surfaces at room temperature using pulsed laser deposition, that shows promising long‐wave infrared emissivity (εLWIR ≈0.42). The hydrophilic C‐BN coatings on glass show excellent environmental stability including high temperature‐high humidity degradation resistance, UV‐light, thermal cycling, freezing condition, and saltwater resilience. Furthermore, the coating shows promising adhesion on the glass surface with full scratch protection. In an actual‐sized building energy simulation for cold‐climates, the intended exterior‐side C‐BN coated low‐E glass shows 2.9% energy savings compared to the interior‐side coated commercial low‐E glass. C‐BN would be a useful coating material for durable and energy‐efficient low‐E glass window technology.

Article Details

Volume / Issue Vol. 37, Issue 38
Published September 01, 2025
ISSN 0935-9648
Publisher Unknown Publisher

Journal Info

Advanced Materials

Unknown Publisher

ISSN: 0935-9648 Physical Sciences

Authors (18)

A

Abhijit Biswas

Department of Materials Science and Nanoengineering Rice University Houston Texas USA

S

Shancheng Wang

Department of Electronic Engineering The Chinese University of Hong Kong Shatin, N.T. Hong Kong SAR 999077 China

C

Cody L. Milne

Department of Physics Arizona State University Tempe AZ 85287 USA

G

Gustavo A. Alvarez

M

Md Akibul Islam

Department of Mechanical & Industrial Engineering University of Toronto 5 King's College Road Toronto M5S 3G8 Canada

T

Tymofii S. Pieshkov

Department of Materials Science and Nanoengineering Rice University Houston Texas 77005 USA

T

Tanguy Terlier

SIMS laboratory, Shared Equipment Authority, Rice University, 6100 Main Street, Houston, Texas 77005, United States

T

Tao Li

J

Jishnu Murukeshan

Department of Materials Science and Nanoengineering Rice University Houston Texas USA

T

Tia Gray

Department of Materials Science and Nanoengineering Rice University Houston Texas USA

J

Jaejun Lee

R

Robert Vajtai

Department of Materials Science and Nanoengineering, Rice University 1 , Houston, Texas 77005,

Y

Yuji Zhao

Department of Electrical and Computer Engineering, Rice University 1 , Houston, Texas 77005,

T

Tobin Filleter

Z

Zhiting Tian

Sibley School of Mechanical and Aerospace Engineering, Cornell University, Ithaca, NY, USA.

A

Arunima K. Singh

Department of Physics, Arizona State University , Tempe, Arizona 85287-1504,

Y

Yi Long

School of Materials Science and Engineering

P

Pulickel M. Ajayan