All‐in‐One Molecule Regulated Buried Interface and Crystallization of Tin–Lead Perovskite for Efficient All‐Perovskite Tandem Solar Cells

X Xiaonan Jin (Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM) Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) Nanjing Tech University Nanjing Jiangsu 211816 China) J Jiupeng Cao (State Key Laboratory of Flexible Electronics (LoFE) & Institute of Advanced Materials (IAM) School of Flexible Electronics (Future Technologies) Nanjing Tech University (NanjingTech) Nanjing China) S Shunan Sui (State Key Laboratory of Flexible Electronics (LoFE) & Institute of Advanced Materials (IAM) School of Flexible Electronics (Future Technologies) Nanjing Tech University (NanjingTech) Nanjing China) J Jiankai Xie (Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM) Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) Nanjing Tech University Nanjing Jiangsu 211816 China) W Wenjian Yan L Lingui Han (Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM) Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) Nanjing Tech University Nanjing Jiangsu 211816 China) J Jibiao Duan (Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM) Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) Nanjing Tech University Nanjing Jiangsu 211816 China) M Meizhu Hu (Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM) Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) Nanjing Tech University Nanjing Jiangsu 211816 China) H Huihui Zhang (Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Av. Països Catalans 16, 43007 Tarragona, Spain) F Fangfang Wang J Jingjin Dong (State Key Laboratory of Flexible Electronics (LoFE) & Institute of Advanced Materials (IAM) School of Flexible Electronics (Future Technologies) Nanjing Tech University (NanjingTech) Nanjing China) A Aifei Wang W Weihao Yuan W Wei Huang T Tianshi Qin

Abstract

Abstract Mixed tin–lead (Sn–Pb) perovskite solar cells (PSCs) are critical for advancing all–perovskite tandem solar technologies, as they resolve the efficiency limitations of single‐junction devices. However, the widely used hole transport layer (HTL) poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) restricts performance and durability due to its acidic nature and moisture absorption. Additionally, the rapid crystallization of Sn‐containing perovskites hinders the fabrication of uniform, high‐quality mixed SnPb perovskite films. To address these challenges, this study incorporates 4‐sulfophthalic acid triammonium salt (SATS) as a multifunctional additive into both the PEDOT:PSS layer and perovskite precursor solution. SATS modifies the physicochemical properties of PEDOT:PSS and slows perovskite crystallization, promoting films with enhanced crystallinity. Through these synergistic effects, the optimized single‐junction SnPb PSCs achieve a power conversion efficiency (PCE) of 23.85%. Integrating these devices into two‐terminal all‐perovskite tandem architectures further delivers a remarkable efficiency of 28.74%.

Article Details

Volume / Issue Vol. 65, Issue 2
Published January 09, 2026
ISSN 1433-7851
Publisher Wiley

Journal Info

Angewandte Chemie International Edition

Wiley

ISSN: 1433-7851 Physical Sciences

Authors (15)

X

Xiaonan Jin

Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM) Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) Nanjing Tech University Nanjing Jiangsu 211816 China

J

Jiupeng Cao

State Key Laboratory of Flexible Electronics (LoFE) & Institute of Advanced Materials (IAM) School of Flexible Electronics (Future Technologies) Nanjing Tech University (NanjingTech) Nanjing China

S

Shunan Sui

State Key Laboratory of Flexible Electronics (LoFE) & Institute of Advanced Materials (IAM) School of Flexible Electronics (Future Technologies) Nanjing Tech University (NanjingTech) Nanjing China

J

Jiankai Xie

Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM) Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) Nanjing Tech University Nanjing Jiangsu 211816 China

W

Wenjian Yan

L

Lingui Han

Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM) Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) Nanjing Tech University Nanjing Jiangsu 211816 China

J

Jibiao Duan

Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM) Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) Nanjing Tech University Nanjing Jiangsu 211816 China

M

Meizhu Hu

Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM) Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM) Nanjing Tech University Nanjing Jiangsu 211816 China

H

Huihui Zhang

Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Av. Països Catalans 16, 43007 Tarragona, Spain

F

Fangfang Wang

J

Jingjin Dong

State Key Laboratory of Flexible Electronics (LoFE) & Institute of Advanced Materials (IAM) School of Flexible Electronics (Future Technologies) Nanjing Tech University (NanjingTech) Nanjing China

A

Aifei Wang

W

Weihao Yuan

W

Wei Huang

T

Tianshi Qin