Advancing Room‐Temperature Magnetic Semiconductors with Organic Radical Charge Transfer Cocrystals
Abstract
AbstractDeveloping purely organic room‐temperature magnetic semiconductors has been a long‐sought goal in the material community toward the simultaneous control of spin and charge. Organic cocrystals, known for their structural versatility and multifunctionality, are ideal candidates for these magnetoelectric coupling applications. However, organic room‐temperature magnetic semiconductor cocrystals have rarely been reported, and their mechanisms remain poorly understood due to the complexity of cocrystal structures. Here, doping organic cocrystals with radicals offers a promising strategy for boosting their magnetism and conductivity while maintaining their cocrystal structures. The fluoranthene‐7,7,8,8‐tetracyanoquinodimethane radical (FA‐HTCNQ•) is constructed through a simple, rapid, and eco‐friendly solution‐processing approach. The conductive FA‐HTCNQ• exhibits excellent room‐temperature ferromagnetism with the coercive fields of 96 Oe and the Curie temperature near 400 K, superior to its structural‐identical undoped counterpart. Meanwhile, the room‐temperature magnetoelectric coupling is demonstrated in the conductive FA‐HTCNQ•. The stronger ferromagnetism and conductivity in organic cocrystals are attributed to the enhanced charge‐transfer (CT) interactions induced by radicals, rather than the spin exchange interactions between these radicals alone. The research manifests the origin of ferromagnetism in organic cocrystals and provides a simple strategy to fabricate pure organic room‐temperature magnetic semiconductor materials for future integrated magnetoelectric devices.
Article Details
Authors (11)
Tingting Li
Siyao Fu
Key Laboratory of Organic Integrated Circuits Ministry of Education Tianjin Key Laboratory of Molecular Optoelectronic Sciences Department of Chemistry School of Science Tianjin University Tianjin 300072 P. R. China
Shuaishuai Ding
State Key Laboratory of Advanced Materials for Intelligent Sensing, Key Laboratory of Organic Integrated Circuit, Ministry of Education & Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, Institute of Molecular Aggregation Science, School of Science
Lingsong Wang
State Key Laboratory of Advanced Materials for Intelligent Sensing Key Laboratory of Organic Integrated Circuits Ministry of Education Tianjin Key Laboratory of Molecular Optoelectronic Sciences Department of Chemistry School of Science Tianjin University Tianjin China
Shuyu Li
State Key Laboratory for Crop Stress Resistance and High-Efficiency Production, Shaanxi Key Laboratory of Agricultural and Environmental Microbiology, College of Life Sciences, Northwest Agriculture and Forestry University
Dong Zhang
School of Physical Science and Technology & Shanghai Key Laboratory of High-Resolution Electron Microscopy
Yunzhe Ke
State Key Laboratory of Advanced Materials for Intelligent Sensing, Key Laboratory of Organic Integrated Circuit, Ministry of Education & Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, Institute of Molecular Aggregation Science, School of Science
Shiyue Sun
State Key Laboratory of Advanced Materials for Intelligent Sensing & Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, Institute of Molecular Aggregation Science, School of Science
Lingjie Sun
State Key Laboratory of Advanced Materials for Intelligent Sensing, Key Laboratory of Organic Integrated Circuit, Ministry of Education & Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science & Institute of Molecular Aggregation Science, Tianjin University
Xiaotao Zhang
Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science, Tianjin University and Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China
Wenping Hu