Advancing Metal–Organic Framework‐Based Composites for Effective Chemical Warfare Agent Detoxification under Real‐World Conditions

Abstract

Abstract Threats from toxic chemical warfare agents (CWAs) persist due to war and terrorist attacks, endangering both human beings and the environment. Metal–organic frameworks (MOFs), which feature ordered pore structures and excellent tunability at both metal/metal cluster nodes and organic linkers, are regarded as the best candidates to directly remove CWAs and their simulants via both physical adsorption and chemically catalyzed hydrolysis or oxidization. MOFs have attracted significant attention in the last two decades that has resulted from the rapid development of MOF‐based materials in both fundamental research and real‐world applications. In this review, the authors focus on the recent advancements in designing and constructing functional MOF‐based materials toward CWAs detoxification and discuss how to bridge the gap between fundamental science and real‐world applications. With detailed summaries from different points of view, this review provides insights into design rules for developing next‐generation MOF‐based materials for protection from both organophosphorus and organosulfur CWAs to mitigate potential threats from CWAs used in wars and terrorism attacks.