A 100,000-Fold Increase in C–H Bond Acidity Gives Palladium a Key Advantage in C(sp <sup>3</sup> )–H Activation Compared to Nickel
L
Lirong Lin
(Department of Chemistry)
T
Tim K. Schramm
(Mulliken Center for Theoretical Chemistry, Clausius Institute for Physical and Theoretical Chemistry, University of Bonn, Beringstraße 4, Bonn 53115, Germany)
P
Pavel Kucheryavy
(Department of Chemistry, Rutgers University − Newark, 73 Warren Street, Newark, New Jersey 07102, United States)
R
Roger A. Lalancette
(Department of Chemistry, Rutgers University − Newark, 73 Warren Street, Newark, New Jersey 07102, United States)
A
Andreas Hansen
(Mulliken Center for Theoretical Chemistry, Clausius Institute for Physical and Theoretical Chemistry)
D
Demyan E. Prokopchuk
(Department of Chemistry)
Article Details
Volume / Issue
Vol. 147, Issue 38
Published
September 24, 2025
Pages
34395-34410
ISSN
0002-7863
Publisher
American Chemical Society
Journal Info
Journal of the American Chemical Society
American Chemical Society
ISSN: 0002-7863 Physical Sciences
Authors (6)
L
Lirong Lin
Department of Chemistry
T
Tim K. Schramm
Mulliken Center for Theoretical Chemistry, Clausius Institute for Physical and Theoretical Chemistry, University of Bonn, Beringstraße 4, Bonn 53115, Germany
P
Pavel Kucheryavy
Department of Chemistry, Rutgers University − Newark, 73 Warren Street, Newark, New Jersey 07102, United States
R
Roger A. Lalancette
Department of Chemistry, Rutgers University − Newark, 73 Warren Street, Newark, New Jersey 07102, United States
A
Andreas Hansen
Mulliken Center for Theoretical Chemistry, Clausius Institute for Physical and Theoretical Chemistry
D
Demyan E. Prokopchuk
Department of Chemistry
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